Synthesis, characterization and crystal structure of holmium complex with β-alanine

被引：0
|
作者：
Ma, LF [1 ]
Wang, LY
Liang, FP
机构：
[1] Luoyang Teachers Coll, Dept Chem, Luoyang 471022, Peoples R China
[2] Guangxi Normal Univ, Dept Chem, Guilin 541004, Peoples R China
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2004年 / 23卷 / 02期
关键词：
holmium complex; beta-alanine; crystal structure;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The complex {[HO2(beta-ala)(6)(H2O)(4)](ClO4)(6).H2O}(n) (beta-ala = beta-alanine) has been synthesized in an aqueous solution with the pH value of 3.5. Its crystal structure was determined by X-ray diffraction method. The crystal is of triclinic, space group P (1) over bar with a = 9.1 99(2), b = 12.870(2), c = 21.620(5) Angstrom, alpha 76.92(1), beta = 81.15(1), gamma = 82.91(1)degrees, V = 2453.2(8) Angstrom(3), Z = 2 and D-c = 2.097 g/cm(3). The structure of the complex can be viewed as a one-dimensional infinite chain. The holmium, ion. is nine-coordinated with a geometry of distorted mono capped square antiprism..
引用
收藏
页码：207 / 212
页数：6
相关论文
共 50 条
  • [21] Synthesis, Crystal structure and Characterization of a New Oxalate Chromium (III) Complex
    RIHAB DRIDI
    SAOUSSEN CHERNI
    MOHAMED FAOUZI ZID
    Journal of Chemical Sciences, 2015, 127 : 1427 - 1433
  • [22] Synthesis, Characterization, and Crystal Structure Investigation of a New Uranyl Complex of Isothiosemicarbazone
    S. A. Yasrebi
    J. T. Mague
    R. Takjoo
    Crystallography Reports, 2021, 66 : 468 - 475
  • [23] Synthesis, Characterization, and Crystal Structure Investigation of a New Uranyl Complex of Isothiosemicarbazone
    Yasrebi, S. A.
    Mague, J. T.
    Takjoo, R.
    CRYSTALLOGRAPHY REPORTS, 2021, 66 (03) : 468 - 475
  • [24] Synthesis, Crystal Structure and Characterization of Macrocyclic Dinuclear Zn(II) Complex
    Bai Jun-Lin
    Zhou Hong
    Pan Zhi-Quan
    Chen Rong
    Hu Jin-Dong
    Wang Ling
    Li Yi-Zhi
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2008, 24 (12) : 1994 - 2001
  • [25] Synthesis, Crystal structure and Characterization of a New Oxalate Chromium (III) Complex
    Dridi, Rihab
    Cherni, Saoussen
    Zid, Mohamed Faouzi
    JOURNAL OF CHEMICAL SCIENCES, 2015, 127 (08) : 1427 - 1433
  • [26] Synthesis, characterization and crystal structure of chlorodibenzyltin(IV) complex with dithiomorpholinocarbamate ligand
    Yin, HD
    Wang, CH
    Ma, CL
    Wang, Y
    CHINESE JOURNAL OF CHEMISTRY, 2002, 20 (09) : 913 - 916
  • [27] Synthesis, Characterization, Crystal Structure and Interaction with DNA of Cobalt(II) Complex
    Hu, Wei-Ji
    Guan, Quan-Yin
    Zhao, Guo-Liang
    ASIAN JOURNAL OF CHEMISTRY, 2013, 25 (07) : 3617 - 3620
  • [28] Synthesis,Characterization and Crystal Structure of a Trinuclear Diorganotin(Ⅳ) Complex with N'-acetylsalicylhydrazide
    崔继春
    乔燕玲
    丁龙华
    尹汉东
    结构化学, 2010, 29 (12) : 1784 - 1787
  • [29] Synthesis and crystal structure of a copper (II) complex with [(4-methylimidazol-1-yl)methylene]-β-alanine
    Long, Lasheng
    Yu, Xiaolan
    Chen, Xiaoming
    Ji, Liangnian
    Zhongshan Daxue Xuebao/Acta Scientiarum Natralium Universitatis Sunyatseni, 1998, 37 (02): : 131 - 132
  • [30] Synthesis and Crystal Structure of a New Dinuclear Holmium(III) Complex with a Bulky Anthracene-Based Carboxylate Ligand
    Liu, Chun-Sen
    Hu, Min
    Zhang, Qiang
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2010, 40 (11) : 1002 - 1005
12345