Crystal structure of 4,5,6,7,8,8-hexachloro-2-(3,4-dimethoxyphenethyl)-3a, 4,7,7a-tetrahydro-1H-4,7-methanoisoindole-1,3(2H)-dione [+solvent]

被引：1

作者：

Manohar, R. ^{[1
,4
]}

Harikrishna, M. ^{[2
]}

Etti, S. Harikrishna ^{[3
]}

Ramanathan, C. ^{[2
]}

Gunasekaran, K. ^{[1
]}

机构：

[1] Univ Madras, Ctr Adv Study Crystallog & Biophys, Guindy Campus, Chennai 600025, Tamil Nadu, India

[2] Pondicherry Univ, Dept Chem, Pondicherry 605014, India

[3] Bharathiar Univ, Dept Med Phys, Coimbatore, Tamil Nadu, India

[4] Florida Int Univ, Ctr Cellular Biol & Pharmacol, Herbert Werthiem Coll Med, Miami, FL 33199 USA

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2019年 / 75卷

关键词：

crystal structure; norbornene; hexachloro; isoindolene; hydrogen bonding; offset pi-pi interaction; C-Cl center dot center dot center dot pi interaction; DERIVATIVES;

D O I：

10.1107/S2056989019004109

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, C19H15Cl6NO4 [+solvent], the sixq-membered ring of the norbornene moiety adopts a boat conformation and the two fiveq-membered rings have envelope conformations. The pyrrolidine ring makes a dihedral angle of 14.83 (12)degrees with the 3,4-dimethoxyphenyl ring, which are attached to each other by an extended N-CH2-CH2-C-ar bridge. In the crystal, the structure features C-H center dot center dot center dot O intermolecular hydrogen bonds, an offset pi-pi interaction [ intercentroid distance = 3.564 (1) angstrom] and a C-Cl center dot center dot center dot pi interaction. The contribution of some disordered solvent to the scattering was removed using the SQUEEZE routine [Spek (2015). Acta Cryst. C71, 9-18] of PLATON. The solvent contribution was not included in the reported molecular weight and density.

引用

页码：562 / +

页数：9

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