Porous phosphorus-based element organic frameworks: A new platform for transition metal catalysts immobilization

被引：33
|
作者：
Fritsch, Julia [1 ]
Drache, Franziska [1 ]
Nickerl, Georg [1 ]
Boehlmann, Winfried [2 ]
Kaskel, Stefan [1 ]
机构：
[1] Tech Univ Dresden, Dept Inorgan Chem, D-01069 Dresden, Germany
[2] Univ Leipzig, Fac Phys & Earth Sci, D-04103 Leipzig, Germany
来源：
MICROPOROUS AND MESOPOROUS MATERIALS | 2013年 / 172卷
关键词：
Element organic framework (EOF); Phosphorus; Transition metals; Wilkinson; Catalysis; PERMANENT POROSITY; SURFACE-AREA; NETWORKS; POLYMERS;
D O I：
10.1016/j.micromeso.2012.12.049
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
EOF-17 (EOF: element organic framework) represents a new member of the EOF family based on phosphorus connected via an organic biphenyl. It is characterized by a specific surface area (BET) of up to 646 m(2)/g and a thermal stability of up to 360 degrees C. As a heterogeneous analog of PPh3 the permanent infiltration of rhodium and palladium complexes is demonstrated. EOF-17 infiltrated with rhodium was successfully tested in the transfer hydrogenation of cyclohexanone. (C) 2013 Elsevier Inc. All rights reserved,
引用
收藏
页码：167 / 173
页数：7
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