A method for measurement of 36Ar without H35Cl interference

Most noble gas analyses are made in static mode when instrument volume is minimized to maintain adequate sensitivity. This makes the building of large instruments to obtain high resolving power impracticable. A method is presented which makes improved use of the available resolving power to remove isobaric interferences, which may be used on multicollector instruments. By arranging that the target mass position on a minor isotope (e.g. Ar-36), from which the interference must be removed, coincides with the approximately 50% point on the side of a major isotope (e.g. 40Ar), it is possible both to set the mass accurately and to verify the mass position and stability during measurements. The peak top of the major isotope is measured in a separate mass step. Calibration measurements are necessary, using different relative amounts of target/interference, to assess residual tailing to the measurement position and also the relative efficiency at the extreme edge of the target peak. The method is demonstrated by using it to obtain Ar-36 measurements free of (HCl)-Cl-35. With samples containing 4 x 10(-15) to 3 x 10(-14) mol of 40Ar, Ar-36/40Ar was measured, without HCl interference, to a 1 sigma precision of 0.5%, only slightly worse than counting statistics. This is potentially useful for 40Ar/39Ar dating, where Ar-36 is used to correct for trapped air, and may be particularly significant for smaller or younger samples. (C) 2015 Elsevier B.V. All rights reserved.