Photomediated RAFT step-growth polymerization with maleimide monomers

被引：10
|
作者：
Clouthier, Samantha Marie [1 ]
Tanaka, Joji [1 ]
You, Wei [1 ]
机构：
[1] Univ N Carolina, Dept Chem, Chapel Hill, NC 27599 USA
来源：
POLYMER CHEMISTRY | 2022年 / 13卷 / 43期
基金：
美国国家科学基金会;
关键词：
LIVING RADICAL POLYMERIZATION; CHAIN TRANSFER AGENTS; DISULFIDES;
D O I：
10.1039/d2py01166b
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Photomediated RAFT step-growth polymerization was performed with and without the presence of a photocatalyst using a trithiocarbonate-based CTA and a maleimide monomer. Under catalyst-free conditions, the polymerization proceeded with an appreciable rate under irradiation with blue and green light, which was extended to red light in the presence of ZnTPP.
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页码：6114 / 6119
页数：6
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