Poly[[bis(4-chlorosalicylato-κO)copper(II)]di-μ-3-pyridylmethanol-κ2N:O;κO:N

被引：13
|
作者：
Maroszová, J
Martiska, L
Valigura, D
Koman, M
Glowiak, T
机构：
[1] Wroclaw B Beirut Univ, Fac Chem, PL-50383 Wroclaw, Poland
[2] Slovak Univ Technol Bratislava, Dept Inorgan Chem, SK-81237 Bratislava, Slovakia
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2006年 / 62卷
关键词：
D O I：
10.1107/S1600536806006817
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The polymeric structure of the title complex, [Cu(C7H4ClO3)(2)-(C6H7NO)(2)](n), at 100 (2) K contains two-dimensional sheets parallel to the ac plane. The Cu-II atom, lying on an inversion centre, has an octahedral coordination environment. It is bonded in a trans-square-planar arrangement to the N atoms of two 3-pyridylmethanol molecules and one carboxylate O atom from each of two 4-chlorosalicylate anions. The axial positions are also occupied by 3-pyridylmethanol, but coordinated through O rather than the pyridyl N atom.
引用
收藏
页码：M1164 / M1166
页数：3
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