Synthesis of aluminate polymer complexes as single-ionic solid electrolytes

被引：53
|
作者：
Onishi, K [1 ]
Matsumoto, M [1 ]
Nakacho, Y [1 ]
Shigehara, K [1 ]
机构：
[1] TOKYO UNIV AGR & TECHNOL, GRAD SCH BIOAPPLICAT & SYST ENGN, KOGANEI, TOKYO 184, JAPAN
来源：
CHEMISTRY OF MATERIALS | 1996年 / 8卷 / 02期
关键词：
D O I：
10.1021/cm950388a
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Main-chain anionic polymers with lithium cations, which have oligo(oxyethylene)aluminate chain backbones attached with two side chains of endo-methoxy[oligo(oxyethylene)], were prepared, and their ionic conductivities are reported. The ac conductivity of aluminate polymer complex was about 10(-6)-10(-7) S cm(-)11 at room temperature. As the constant current was observed for [Li/aluminate polymer complex/Li] cells under de electric field, the single-ionic conduction was confirmed.
引用
收藏
页码：469 / 472
页数：4
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