Design and synthesis of anthracene-based bispyridinium amides: anion binding, cell staining and DNA interaction studies

被引：25

作者：

Ghosh, Kumaresh ^{[1
]}

Sarkar, Avik Ranjan ^{[1
]}

Ghorai, Atanu ^{[2
]}

Ghosh, Utpal ^{[2
]}

机构：

[1] Univ Kalyani, Dept Chem, Kalyani 741235, W Bengal, India

[2] Univ Kalyani, Dept Biochem & Biophys, Kalyani 741235, W Bengal, India

来源：

NEW JOURNAL OF CHEMISTRY | 2012年 / 36卷 / 05期

关键词：

FLUORESCENT CHEMOSENSOR; SELECTIVE FLUORESCENT; MOLECULAR RECOGNITION; ABIOTIC GUANIDINIUM; RECEPTORS; FLUORIDE; COMPLEXATION; INTERCALATION; PHOSPHATE; SENSORS;

D O I：

10.1039/c2nj21024j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The design and synthesis of anthracene labeled bispyridinium amides 1-4 along with their anion binding, cell staining and DNA interaction studies are reported. All the chemosensors exhibit significant response towards H2PO4 in CH3CN. Furthermore, sensors 2 and 3 are quite interesting for the selective sensing of aliphatic dicarboxylates. Among these compounds, 1 is found to be useful in cell staining. Also all of them exhibit significant interaction with DNA. All these properties are found to be dependent on the nature of the spacer that holds the pyridinium binding sites.

引用

页码：1231 / 1245

页数：15

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