Activated carbon/graphene composites with high-rate performance as electrode materials for electrochemical capacitors

被引:36
|
作者
Jiang, Lei [1 ,3 ,4 ]
Yan, Jingwang [1 ,2 ]
Zhou, Ying [3 ]
Hao, Lixing [1 ,2 ]
Xue, Rong [1 ,2 ]
Jiang, Liang [1 ,2 ]
Yi, Baolian [1 ,2 ]
机构
[1] Chinese Acad Sci, Dalian Inst Chem Phys, Lab Supercapacitors, Dalian 116023, Peoples R China
[2] Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China
[3] Dalian Univ Technol, Sch Chem Engn, Liaoning Key Lab Energy Mat & Chem Engn, Carbon Res Lab,State Key Lab Fine Chem, Dalian 116024, Peoples R China
[4] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
基金
美国国家科学基金会;
关键词
Graphene; Glucose; Activated carbon; Electrochemical capacitors; CARBON MATERIALS; PORE-SIZE; ENERGY; STORAGE; PRECURSOR; NANOTUBES; STARCH; COAL;
D O I
10.1007/s10008-013-2217-x
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Glucose-derived activated carbon (GAC)/reduced graphene oxide (RGO) composites are prepared by pre-carbonization of the precursors (aqueous mixture of glucose and graphene oxide) and KOH activation of the pyrolysis products. The effect of the mass ratio of graphene oxide (GO) in the precursor on the electrochemical performance of GAC/RGO composites as electrode materials for electrochemical capacitors is investigated. It is found that the thermally reduced graphene oxide sheets serves as a wrinkled carrier to support the activated carbon particles after activation. The pore size distribution and surface area are depended on the mass ratio of GO. Besides, the rate capability of GAC is improved by the introduction of GO in the precursor. The highest specific capacitance of 334 F g(-1) is achieved for the GAC/RGO composite prepared from the precursor with a GO mass ratio of 3 %.
引用
收藏
页码:2949 / 2958
页数:10
相关论文
共 50 条
  • [41] High-Rate Electrochemical Capacitors Based on Ordered Mesoporous Silicon Carbide-Derived Carbon
    Korenblit, Yair
    Rose, Marcus
    Kockrick, Emanuel
    Borchardt, Lars
    Kvit, Alexander
    Kaskel, Stefan
    Yushin, Gleb
    ACS NANO, 2010, 4 (03) : 1337 - 1344
  • [42] Graphene/cotton composite fabrics as flexible electrode materials for electrochemical capacitors
    Xu, Ling-Li
    Guo, Mei-Xia
    Liu, Si
    Bian, Shao-Wei
    RSC ADVANCES, 2015, 5 (32): : 25244 - 25249
  • [43] Graphene sheets anchored with ZnO nanocrystals as electrode materials for electrochemical capacitors
    Hsieh, Chien-Te
    Lin, Jiun-Sheng
    Chen, Yu-Fu
    Lin, Chi-Yuan
    Li, Wen-Yen
    MATERIALS CHEMISTRY AND PHYSICS, 2014, 143 (02) : 853 - 859
  • [44] Facilitation of High-Rate NADH Electrocatalysis Using Electrochemically Activated Carbon Materials
    Li, Hanzi
    Li, Rui
    Worden, Robert M.
    Barton, Scott Calabrese
    ACS APPLIED MATERIALS & INTERFACES, 2014, 6 (09) : 6687 - 6696
  • [45] Enhanced electrochemical performance of porous activated carbon by forming composite with graphene as high-performance supercapacitor electrode material
    Zhi-Hang Wang
    Jia-Ying Yang
    Xiong-Wei Wu
    Xiao-Qing Chen
    Jin-Gang Yu
    Yu-Ping Wu
    Journal of Nanoparticle Research, 2017, 19
  • [46] Enhanced electrochemical performance of porous activated carbon by forming composite with graphene as high-performance supercapacitor electrode material
    Wang, Zhi-Hang
    Yang, Jia-Ying
    Wu, Xiong-Wei
    Chen, Xiao-Qing
    Yu, Jin-Gang
    Wu, Yu-Ping
    JOURNAL OF NANOPARTICLE RESEARCH, 2017, 19 (02)
  • [47] Deposition of MnO2 nanoneedles on carbon nanotubes and graphene nanosheets as electrode materials for electrochemical capacitors
    Hsieh, Chien-Te
    Tzou, Dong-Ying
    Lee, Wen-Yen
    Hsu, Jo-Pei
    JOURNAL OF ALLOYS AND COMPOUNDS, 2016, 660 : 99 - 107
  • [48] Brewery waste derived activated carbon for high performance electrochemical capacitors and lithium-ion capacitors
    Magar, Sandesh Darlami
    Leibing, Christian
    Luis Gomez-Urbano, Juan
    Cid, Rosalia
    Carriazo, Daniel
    Balducci, Andrea
    ELECTROCHIMICA ACTA, 2023, 446
  • [49] Nanostructured Ni compounds as electrode materials towards high-performance electrochemical capacitors
    Ruan, Yunjun
    Wang, Chundong
    Jiang, Jianjun
    JOURNAL OF MATERIALS CHEMISTRY A, 2016, 4 (38) : 14509 - 14538
  • [50] Electrochemical Performance of Activated Carbon Electrode Materials with Various Post Treatments for EDLC
    Lee, Eunji
    Kwon, Soon Hyung
    Choi, Pooreum
    Jung, Ji Chul
    Kim, Myung-Soo
    KOREAN JOURNAL OF MATERIALS RESEARCH, 2014, 24 (06): : 285 - 292