Activated carbon/graphene composites with high-rate performance as electrode materials for electrochemical capacitors

被引:36
|
作者
Jiang, Lei [1 ,3 ,4 ]
Yan, Jingwang [1 ,2 ]
Zhou, Ying [3 ]
Hao, Lixing [1 ,2 ]
Xue, Rong [1 ,2 ]
Jiang, Liang [1 ,2 ]
Yi, Baolian [1 ,2 ]
机构
[1] Chinese Acad Sci, Dalian Inst Chem Phys, Lab Supercapacitors, Dalian 116023, Peoples R China
[2] Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China
[3] Dalian Univ Technol, Sch Chem Engn, Liaoning Key Lab Energy Mat & Chem Engn, Carbon Res Lab,State Key Lab Fine Chem, Dalian 116024, Peoples R China
[4] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
基金
美国国家科学基金会;
关键词
Graphene; Glucose; Activated carbon; Electrochemical capacitors; CARBON MATERIALS; PORE-SIZE; ENERGY; STORAGE; PRECURSOR; NANOTUBES; STARCH; COAL;
D O I
10.1007/s10008-013-2217-x
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Glucose-derived activated carbon (GAC)/reduced graphene oxide (RGO) composites are prepared by pre-carbonization of the precursors (aqueous mixture of glucose and graphene oxide) and KOH activation of the pyrolysis products. The effect of the mass ratio of graphene oxide (GO) in the precursor on the electrochemical performance of GAC/RGO composites as electrode materials for electrochemical capacitors is investigated. It is found that the thermally reduced graphene oxide sheets serves as a wrinkled carrier to support the activated carbon particles after activation. The pore size distribution and surface area are depended on the mass ratio of GO. Besides, the rate capability of GAC is improved by the introduction of GO in the precursor. The highest specific capacitance of 334 F g(-1) is achieved for the GAC/RGO composite prepared from the precursor with a GO mass ratio of 3 %.
引用
收藏
页码:2949 / 2958
页数:10
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