Photoinduced Metal-Free Atom Transfer Radical Polymerization of Biomass-Based Monomers

被引：64

作者：

Wang, Jifu ^{[1
,2
,3
,4
,5
]}

Yuan, Liang ^{[5
]}

Wang, Zhongkai ^{[5
]}

Rahman, Md Anisur ^{[5
]}

Huang, Yucheng ^{[5
]}

Zhu, Tianyu ^{[5
]}

Wang, Ruibo ^{[6
]}

Cheng, Jianjun ^{[6
]}

Wang, Chunpeng ^{[1
,2
,3
,4
]}

Chu, Fuxiang ^{[1
,2
,3
,4
]}

Tang, Chuanbing ^{[5
]}

机构：

[1] CAF, Inst Chem Ind Forest Prod, Nanjing 210042, Jiangsu, Peoples R China

[2] Natl Engn Lab Biomass Chem Utilizat, Nanjing 210042, Jiangsu, Peoples R China

[3] SFA, Key & Lab Forest Chem Engn, Nanjing 210042, Jiangsu, Peoples R China

[4] Key Lab Biomass Energy & Mat, Nanjing 210042, Jiangsu, Peoples R China

[5] Univ South Carolina, Dept Chem & Biochem, Columbia, SC 29208 USA

[6] Univ Illinois, Dept Mat Sci & Engn, Urbana, IL 61801 USA

来源：

MACROMOLECULES | 2016年 / 49卷 / 20期

基金：

美国国家科学基金会; 中国国家自然科学基金;

关键词：

SUSTAINABLE THERMOPLASTIC ELASTOMERS; RING-OPENING POLYMERIZATION; VISIBLE-LIGHT; RENEWABLE RESOURCES; BLOCK-COPOLYMERS; DRUG-DELIVERY; RAFT PROCESS; PLANT OIL; POLYMERS; ROSIN;

D O I：

10.1021/acs.macromol.6b01997

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Well-defined polymers derived from biomass feedstock (e.g., soybean oil, rosin acid, and furfural) were successfully prepared by metal-free atom transfer radical polymerization (ATRP). In the presence of photoredox catalysts and UV irradiation, three biomass-based methacrylate monomers were efficiently polymerized with good control over molecular weight and dispersity. NMR. and MALDI-TOF MS confirmed high fidelity of chain end groups originated from initiators. Furthermore, block copolymers from these monomers were also achieved through chain extension by metal-free ATRP.

引用

页码：7709 / 7717

页数：9

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