Absorption of NO from simulated flue gas by using NaClO2/(NH4)2CO3 solutions in a stirred tank reactor

被引：25
|
作者：
Guo, Rui-Tang [1 ,2 ]
Pan, Wei-Guo [1 ,2 ]
Ren, Jian-Xing [1 ,2 ]
Zhang, Xiao-Bo [1 ,2 ]
Jin, Qiang [2 ,3 ]
机构：
[1] Shanghai Univ Elect Power, Sch Energy Source & Environm Engn, Shanghai, Peoples R China
[2] Shanghai Power Generat Environm Protect Res Ctr, Shanghai, Peoples R China
[3] SEC IHI Power Generat Environm Protect Engn Co Lt, Shanghai, Peoples R China
来源：
KOREAN JOURNAL OF CHEMICAL ENGINEERING | 2013年 / 30卷 / 01期
关键词：
NO; (NH4)(2)CO3; Absorption; Kinetics; REMOVAL; SO2; OXIDATION;
D O I：
10.1007/s11814-012-0121-1
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Experiments were performed in a stirred tank reactor to study the absorption kinetics of NO into aqueous solutions of NaClO2/(NH4)(2)CO3 solutions. The absorption process is a fast pseudo-reaction, and the reaction was found to be second-order with respect to NO and first-order with respect to NaClO2, respectively. The frequency factor and the average activation energy of this reaction were 4.56 x 10(11) m(6)/(mol(2) s) and 33.01 kJ/mol respectively. The absorption rate of NO increased with increasing reaction temperature, but decreased with increasing (NH4)(2)CO3 solution.
引用
收藏
页码：101 / 104
页数：4
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