Liquid phase oxidation of 2-methyl pyridine to 2-pyridinecarboxylic acid over cobalt-doped SBA-3

被引：7

作者：

Li, Bin ^{[1
]}

Li, Lin ^{[1
]}

Sun, Lin ^{[1
]}

Xia, Fei ^{[1
]}

Wang, Siping ^{[1
]}

Wang, Jiaqiang ^{[1
]}

机构：

[1] Yunnan Univ, Minist Educ, Dept Appl Chem, Key Lab Med Chem Nat Resource, Kunming 650091, Peoples R China

来源：

CATALYSIS COMMUNICATIONS | 2008年 / 9卷 / 13期

关键词：

cobalt-doped SBA-3; selective oxidation of 2-methyl pyridine; 2-pyridinecarboxylic acid;

D O I：

10.1016/j.catcom.2008.05.027

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Cobalt-doped SBA-3 was synthesized by cogellation method and was used as a catalyst for the oxidation of 2-methyl pyridine in acetic acid using aqueous hydrogen peroxide as oxidant. The catalyst exhibited very high substrate conversion (98%) and good product (2-pyridinecarboxylic acid) selectivity (93%). Fast hot catalyst filtration experiment proved that the catalyst acted as a heterogeneous one and it can be reused two times without losing its activity to a greater extent. The catalyst was characterized by X-ray diffraction, N-2 physisorption, diffuse reflectance UV-vis, and FT-IR. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：2287 / 2290

页数：4

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