A lithium-organic framework with coordinatively unsaturated metal sites that reversibly binds water

被引：18

作者：

El Osta, Racha ^{[1
]}

Frigoli, Michel ^{[1
]}

Marrot, Jerome ^{[1
]}

Guillou, Nathalie ^{[1
]}

Chevreau, Hubert ^{[1
]}

Walton, Richard I. ^{[2
]}

Millange, Franck ^{[1
]}

机构：

[1] Univ Versailles, Inst Lavoisier Versailles, UMR CNRS 8180, F-78035 Versailles, France

[2] Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 86期

关键词：

STRUCTURAL-CHARACTERIZATION; ADSORPTION; CATALYSIS; ALKOXIDE; BEHAVIOR; SORPTION; ACID;

D O I：

10.1039/c2cc35861a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis and characterisation of a three-dimensional lithium-organic framework MIL-145 is described, which upon thermal treatment yields a second open framework, MIL-146, that contains four and three-coordinate lithium centres: the coordinatively unsaturated trigonal planar lithium centres are able to reversibly bind water with crystallinity maintained, while the dehydrated phase shows preferential adsorption of CO2 over N-2.

引用

页码：10639 / 10641

页数：3

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