A lithium-organic framework with coordinatively unsaturated metal sites that reversibly binds water

被引：18
|
作者：
El Osta, Racha [1 ]
Frigoli, Michel [1 ]
Marrot, Jerome [1 ]
Guillou, Nathalie [1 ]
Chevreau, Hubert [1 ]
Walton, Richard I. [2 ]
Millange, Franck [1 ]
机构：
[1] Univ Versailles, Inst Lavoisier Versailles, UMR CNRS 8180, F-78035 Versailles, France
[2] Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England
来源：
CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 86期
关键词：
STRUCTURAL-CHARACTERIZATION; ADSORPTION; CATALYSIS; ALKOXIDE; BEHAVIOR; SORPTION; ACID;
D O I：
10.1039/c2cc35861a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The synthesis and characterisation of a three-dimensional lithium-organic framework MIL-145 is described, which upon thermal treatment yields a second open framework, MIL-146, that contains four and three-coordinate lithium centres: the coordinatively unsaturated trigonal planar lithium centres are able to reversibly bind water with crystallinity maintained, while the dehydrated phase shows preferential adsorption of CO2 over N-2.
引用
收藏
页码：10639 / 10641
页数：3
相关论文
共 50 条
  • [1] Controlled Reducibility of a Metal-Organic Framework with Coordinatively Unsaturated Sites for Preferential Gas Sorption
    Yoon, Ji Woong
    Seo, You-Kyong
    Hwang, Young Kyu
    Chang, Jong-San
    Leclerc, Herve
    Wuttke, Stefan
    Bazin, Philippe
    Vimont, Alexandre
    Daturi, Marco
    Bloch, Emily
    Llewellyn, Philip L.
    Serre, Christian
    Horcajada, Patricia
    Greneche, Jean-Marc
    Rodrigues, Alirio E.
    Ferey, Gerard
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (34) : 5949 - 5952
  • [2] Porous metal-organic framework with coordinatively unsaturated MnII sites:: Sorption properties for various gases
    Moon, Hoi Ri
    Kobayashi, Norihito
    Suh, Myunghyun Paik
    INORGANIC CHEMISTRY, 2006, 45 (21) : 8672 - 8676
  • [3] Coordinatively unsaturated metal sites (open metal sites) in metal-organic frameworks: design and applications
    Kokcam-Demir, Ulku
    Goldman, Anna
    Esrafili, Leili
    Gharib, Maniya
    Morsali, Ali
    Weingart, Oliver
    Janiak, Christoph
    CHEMICAL SOCIETY REVIEWS, 2020, 49 (09) : 2751 - 2798
  • [4] High styrene/ethylbenzene selectivity in a metal-organic framework with coordinatively unsaturated cobalt(II) sites
    Kim, Seung-Ik
    Kim, Ah-Reum
    Kim, Seo-Yul
    Lee, Ju-Yeop
    Bae, Youn-Sang
    SEPARATION AND PURIFICATION TECHNOLOGY, 2020, 242
  • [5] A metal-organic framework with coordinatively unsaturated metal centers and microporous structure
    Mu, Bin
    Huang, Yougui
    Walton, Krista S.
    CRYSTENGCOMM, 2010, 12 (08): : 2347 - 2349
  • [6] Metal Organic Framework with Coordinatively Unsaturated Sites as Efficient Fenton-like Catalyst for Enhanced Degradation of Sulfamethazine
    Tang, Juntao
    Wang, Jianlong
    ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2018, 52 (09) : 5367 - 5377
  • [7] Constructing tunable coordinatively unsaturated sites in Fe-based metal-organic framework for effective degradation of pharmaceuticals in water: Performance and mechanism
    Li, Yunyun
    Li, Xiang
    Wang, Bo
    CHEMOSPHERE, 2023, 310
  • [8] Competitive Guest Binding in a Metal-Organic Framework with Coordinatively Unsaturated Metals
    Woo, Hochul
    Matzger, Adam J.
    ACS MATERIALS LETTERS, 2025, 7 (02): : 450 - 456
  • [9] A structurally flexible triazolate-based metal-organic framework featuring coordinatively unsaturated copper(I) sites
    Schmieder, P.
    Denysenko, D.
    Grzywa, M.
    Magdysyuk, O.
    Volkmer, D.
    DALTON TRANSACTIONS, 2016, 45 (35) : 13853 - 13862
  • [10] Designing coordinatively unsaturated metal sites in bimetallic organic frameworks for oxygen evolution reaction
    Rajasekaran, S.
    Reghunath, B. S.
    Devi, K. R. Sunaja
    Pinheiro, D.
    MATERIALS TODAY CHEMISTRY, 2023, 31
12345