"Shape-Coding": Morphology-Based Information System for Polymers and Composites

被引:14
|
作者
Pansare, Amol, V [3 ]
Chhatre, Shraddha Y. [4 ]
Khairkar, Shyam R. [5 ]
Bell, Jeffrey G. [2 ]
Barbezat, Michel [3 ]
Chakrabarti, Subhananda [1 ]
Nagarkar, Amit A. [2 ]
机构
[1] Indian Inst Technol, Dept Elect Engn, Mumbai 400076, Maharashtra, India
[2] Harvard Univ, Dept Chem & Chem Biol, Cambridge, MA 02138 USA
[3] Empa, Mech Syst Engn, Swiss Fed Labs Mat Sci & Technol, CH-8600 Dubendorf, Switzerland
[4] Natl Chem Lab NCL, Pune 411008, Maharashtra, India
[5] Natl Inst Mat Sci, Res & Serv Div Mat Data & Integrated Syst MaDIS, Tsukuba, Ibaraki 3050047, Japan
基金
瑞士国家科学基金会;
关键词
solid-state synthesis; nanoparticle morphology control; epoxy composites; barcoding chemical encryption; CARBON; NUCLEATION; RESIN;
D O I
10.1021/acsami.0c05314
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Fiber-reinforced composites have become the material of choice for aerospace structures because of their favorable strength-to-weight ratio. Given the increasing amounts of counterfeit composite parts showing up in the complex aerospace supply chain, it is absolutely vital to track a composite part throughout its lifecycle-from production to usage and to disposal. Existing barcoding methods are invasive, affect the structural properties of composites, and/or are vulnerable to tampering. We describe a universal method to store information in fiber-reinforced composites based on solid-state in situ reduction leading to embedded nanoparticles with controlled morphologies. This simple, cost-effective, mild, surfactant-free, and one-step protocol for the fabrication of embedded platinum nanostructures leads to morphology-based barcodes for polymeric composites. We also describe a coding methodology wherein a 1 x 1 cm code can represent 3.4 billion parts to 95 trillion parts, depending on the resolution required along with access to morphology-based chemical encryption systems.
引用
收藏
页码:27555 / 27561
页数:7
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