Metal-ligand cooperativity across two sites of a square planar iron(ii) complex ligated by a tetradentate PNNP ligand

被引：16

作者：

Hatzis, Gregory P. ^{[1
]}

Thomas, Christine M. ^{[1
]}

机构：

[1] Ohio State Univ, Dept Chem & Biochem, 100 W 18th Ave, Columbus, OH 43210 USA

来源：

CHEMICAL COMMUNICATIONS | 2020年 / 56卷 / 61期

关键词：

ASYMMETRIC TRANSFER HYDROGENATION; BORANE; CATALYSIS; GEOMETRY; STATE;

D O I：

10.1039/d0cc02152k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An iron(ii) complex with a square planar geometry andS= 1 ground state was synthesized using a rigid tetradentate bisphosphine-bisamide [PNNP](2-)ligand. This complex was shown to bind an equivalent of PMe(3)to produce a five-coordinate low spin complex, and to react with two equivalents of borane reagentsviaaddition of two B-H bonds across the metal-amide bonds in a metal-ligand cooperative fashion.

引用

页码：8611 / 8614

页数：4

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