Microphyllandiolide, a New Diterpene with an Unprecedented Skeleton from Salvia microphylla

被引：26
|
作者：
Bautista, Elihu [1 ]
Alfredo Toscano, Ruben [1 ]
Ortega, Alfredo [1 ]
机构：
[1] Univ Nacl Autonoma Mexico, Inst Quim, Mexico City 04510, DF, Mexico
来源：
ORGANIC LETTERS | 2013年 / 15卷 / 13期
关键词：
SALVINORIN;
D O I：
10.1021/ol401022c
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Microphyllandiolide (1), an unprecedented rearranged clerodane-type diterpene with a 9/3 bicyclic ring system, was isolated from the aerial parts of Salvia microphylla Kunth. Its structure was elucidated by analysis of its spectroscopic data and confirmed by single crystal X-ray diffraction analysis. A possible biogenesis for microphyllandiolide (1) is proposed.
引用
收藏
页码：3210 / 3213
页数：4
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