Microphyllandiolide, a New Diterpene with an Unprecedented Skeleton from Salvia microphylla

被引：26
|
作者：
Bautista, Elihu [1 ]
Alfredo Toscano, Ruben [1 ]
Ortega, Alfredo [1 ]
机构：
[1] Univ Nacl Autonoma Mexico, Inst Quim, Mexico City 04510, DF, Mexico
来源：
ORGANIC LETTERS | 2013年 / 15卷 / 13期
关键词：
SALVINORIN;
D O I：
10.1021/ol401022c
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Microphyllandiolide (1), an unprecedented rearranged clerodane-type diterpene with a 9/3 bicyclic ring system, was isolated from the aerial parts of Salvia microphylla Kunth. Its structure was elucidated by analysis of its spectroscopic data and confirmed by single crystal X-ray diffraction analysis. A possible biogenesis for microphyllandiolide (1) is proposed.
引用
收藏
页码：3210 / 3213
页数：4
相关论文
共 50 条
  • [1] Salviskinone A, a diterpene with a new skeleton from Salvia przewalskii
    Ohsaki, Ayumi
    Kawamata, Shunsuke
    Ozawa, Masaaki
    Kishida, Akio
    Gong, Xun
    Kuroda, Chiaki
    TETRAHEDRON LETTERS, 2011, 52 (12) : 1375 - 1377
  • [2] Hydrangenone, a New Isoprenoid with an Unprecedented Skeleton from Salvia hydrangea
    Farimani, M. Moridi
    Taheri, Salman
    Ebrahimi, Samad N.
    Bahadori, M. Babak
    Khavasi, Hamid R.
    Zimmermann, Stefanie
    Brun, Reto
    Hamburger, Matthias
    ORGANIC LETTERS, 2012, 14 (01) : 166 - 169
  • [3] Micranthanone A, a New Diterpene with an Unprecedented Carbon Skeleton from Rhododendron micranthum
    Zhang, Mengke
    Zhu, Yan
    Zhan, Guanqun
    Shu, Penghua
    Sa, Rongjian
    Lei, Liang
    Xiang, Ming
    Xue, Yongbo
    Luo, Zengwei
    Wan, Qian
    Yao, Guangmin
    Zhang, Yonghui
    ORGANIC LETTERS, 2013, 15 (12) : 3094 - 3097
  • [4] TRICHOAURANTIANOLIDE-A, A NEW DITERPENE WITH AN UNPRECEDENTED CARBON SKELETON FROM TRICHOLOMA-AURANTIUM
    INVERNIZZI, AG
    VIDARI, G
    VITAFINZI, P
    TETRAHEDRON LETTERS, 1995, 36 (11) : 1905 - 1908
  • [5] Przewalskin B, a novel diterpenoid with an unprecedented skeleton from Salvia przewalskii maxim
    Xu, Gang
    Hou, Ai-Jun
    Zheng, Yong-Tang
    Zhao, Yu
    Li, Xiao- Li
    Peng, Li-Yan
    Zhao, Qin-Shi
    ORGANIC LETTERS, 2007, 9 (02) : 291 - 293
  • [6] ABIETANE DITERPENE QUINONES AND A NEW DITERPENE EPOXIDE FROM SALVIA-MOORCRAFTIANA
    BAKSHI, B
    MULCHANDANI, NB
    SHANKAR, J
    PROCEEDINGS OF THE INDIAN ACADEMY OF SCIENCES-CHEMICAL SCIENCES, 1986, 97 (02): : 167 - 170
  • [7] A new antibacterial diterpene from the roots of Salvia caespitosa
    Ulubelen, A
    Öksüz, S
    Topcu, G
    Gören, AC
    Bozok-Johansson, C
    Çelik, C
    Kökdil, G
    Voelter, W
    NATURAL PRODUCT LETTERS, 2001, 15 (05): : 307 - 314
  • [8] A NEW DITERPENE ACID FROM SALVIA-TOMENTOSA
    ULUBELEN, A
    MISKI, M
    MABRY, TJ
    JOURNAL OF NATURAL PRODUCTS, 1981, 44 (01): : 119 - 124
  • [9] Salvidorol, a nor-abietane diterpene with a rare carbon skeleton and two abietane diterpene derivatives from Salvia dorrii
    Ahmed, AA
    Mohamed, AEHH
    Karchesy, J
    Asakawa, Y
    PHYTOCHEMISTRY, 2006, 67 (05) : 424 - 428
  • [10] A NEW DITERPENE WITH A TOTARANE SKELETON FROM VELLOZIA FLAVICANS
    PINTO, AC
    ZOCHER, DHT
    REZENDE, CM
    GOTTLIEB, HE
    NATURAL PRODUCT LETTERS, 1995, 6 (03): : 209 - 213
12345