catena-Poly[[bis(5-chloro-2-nitrobenzoato)copper(II)]-bis(μ-5-chloro-2-nitrobenzoato)]

被引：4
|
作者：
Lim, Eng Khoon [2 ]
Teoh, Siang Guan [2 ]
Razak, Ibrahim Abdul [1 ]
Fun, Hoong-Kun [1 ]
机构：
[1] Univ Sains Malaysia, Sch Phys, Xray Crystallog Unit, Usm 11800, Penang, Malaysia
[2] Univ Sains Malaysia, Sch Chem Sci, Usm 11800, Penang, Malaysia
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷
关键词：
CRYSTAL-STRUCTURE;
D O I：
10.1107/S1600536809001895
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title compound, [Cu-2(C7H3ClNO4)(4)](n), the coordination geometry around each Cu-II ion is distorted square-pyramidal. The CuO5 coordination is formed by five O atoms from the carboxylate groups of five 5-chloro-2-nitrobenzoate ligands. This coordination leads to the formation of centrosymmetric binuclear units which are edge-shared, forming a linear chain along the a axis, with the CuII ions alternately separated by 2.5891 (4) and 3.1763 (4) angstrom. The chains are interconnected into a three-dimensional network by C-H center dot center dot center dot O interactions.
引用
收藏
页码：M211 / U863
页数：12
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