Characterization of plasticized grafted natural rubber-30% poly (methyl methacrylate) (MG30) based polymer electrolytes

被引：0
|
作者：
Zaki, N. H. M. [1 ]
Mahmud, Z. S. [1 ]
Adam, N. I. [1 ]
Ahmad, A. H.
Ali, A. M. M. [2 ]
Yahya, M. Z. A. [3 ]
机构：
[1] Univ Teknol MARA, Fac Appl Sci, Shah Alam 40450, Selangor, Malaysia
[2] Univ Teknol MARA, Inst Sci, Shah Alam 40450, Selangor, Malaysia
[3] Natl Def Univ Malaysia, Dept Phys, Kuala Lumpur 57000, Malaysia
来源：
IEEE SYMPOSIUM ON BUSINESS, ENGINEERING AND INDUSTRIAL APPLICATIONS (ISBEIA 2012) | 2012年
关键词：
MG30; Ionic conductivity; XRD; UV-Visible; IONIC-CONDUCTIVITY; RUBBER; BATTERIES; PMMA;
D O I：
暂无
中图分类号：
TM [电工技术]; TN [电子技术、通信技术];
学科分类号：
0808 ; 0809 ;
摘要：
This study explained on the effect of plasticizer ethylene carbonate (EC) on the properties of 30% poly (methyl methacrylate) grafted natural rubber grafted (MG30) doped with ammonium triflate (NH4CF3SO3) are investigated. The influence of salt concentration and with different proportion of plasticizer on the conductivity has been presented. The ac impedance study showed the conductivity reaches up to 10(-4) Scm(-1) at room temperature for the EC plasticized sample. The conductivity temperature-dependent studies depicted the plasticized and unplasticized MG30-ammonium salt complexes deviated from Arrhenius behavior. The X-Ray diffraction (XRD) spectra analysis demonstrated the incorporation of plasticizer was improved the amorphousness of MG30-NH4CF3SO3 electrolyte films. The energy band gap (E-g) was found to decrease with the increasing of plasticizer content.
引用
收藏
页码：705 / 708
页数：4
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