Lewis Basic Selenium Catalyzed Chloroamidation of Olefins Using Nitriles as the Nucleophiles

被引：64
|
作者：
Tay, Daniel Weiliang [1 ,2 ]
Tsoi, Ivan Tan [1 ,2 ]
Er, Jun Cheng [1 ]
Leung, Gulice Yiu Chung [2 ]
Yeung, Ying-Yeung [1 ]
机构：
[1] Natl Univ Singapore, Dept Chem, Singapore 117543, Singapore
[2] A STAR Inst Chem & Engn Sci, Singapore 138667, Singapore
来源：
ORGANIC LETTERS | 2013年 / 15卷 / 06期
关键词：
STEREOSELECTIVE AMINOHALOGENATION; ASYMMETRIC BROMOLACTONIZATION; OXIDATION; THIOCARBAMATE; ACTIVATION; ALKENES; ACIDS; HALOAMIDATION; DIAMINES; NITROGEN;
D O I：
10.1021/ol400249x
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A Lewis base catalyzed chloroamidation of olefinic substrates was achieved using diphenyl selenide as the catalyst. The reaction conditions are mild and suitable for a wide range of substrates including those which are acid labile.
引用
收藏
页码：1310 / 1313
页数：4
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