Lewis Basic Selenium Catalyzed Chloroamidation of Olefins Using Nitriles as the Nucleophiles

被引：64

作者：

Tay, Daniel Weiliang ^{[1
,2
]}

Tsoi, Ivan Tan ^{[1
,2
]}

Er, Jun Cheng ^{[1
]}

Leung, Gulice Yiu Chung ^{[2
]}

Yeung, Ying-Yeung ^{[1
]}

机构：

[1] Natl Univ Singapore, Dept Chem, Singapore 117543, Singapore

[2] A STAR Inst Chem & Engn Sci, Singapore 138667, Singapore

来源：

ORGANIC LETTERS | 2013年 / 15卷 / 06期

关键词：

STEREOSELECTIVE AMINOHALOGENATION; ASYMMETRIC BROMOLACTONIZATION; OXIDATION; THIOCARBAMATE; ACTIVATION; ALKENES; ACIDS; HALOAMIDATION; DIAMINES; NITROGEN;

D O I：

10.1021/ol400249x

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A Lewis base catalyzed chloroamidation of olefinic substrates was achieved using diphenyl selenide as the catalyst. The reaction conditions are mild and suitable for a wide range of substrates including those which are acid labile.

引用

页码：1310 / 1313

页数：4

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