Bisbenzimidazole diamide copper(II) complexes and their reactivity towards superoxide

被引：0
|
作者：
Tehlan, S [1 ]
Upadhyay, S [1 ]
Mathur, P [1 ]
机构：
[1] Univ Delhi, Dept Chem, Delhi 110007, India
来源：
JOURNAL OF THE INDIAN CHEMICAL SOCIETY | 2005年 / 82卷 / 12期
关键词：
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A benzimidazole-based diamide ligand N, N'-bis(2-benzimidazolylmethyl) propane diamide (GBMA) and N, N'-bis(N-ethyl-2-benzimidazolylmethyl)hexane diamide (E-GBHA) have been synthesized and utilized to prepare copper(II) complexes of general composition [Cu(L)X]X, where X = Cl-, NO3-, SCN- and L = GBMA, E-GBHA. The EPR spectra reveal the presence of distorted tetragonal copper site in the complexes with g(parallel to) > g(perpendicular to) > 2. The complexs display a quasi-reversible redox wave due to the Cu-II/Cu-I redox couple with E-1/2 varying in the order Cl- < NO3- congruent to SCN-. The copper(II) complexes react by quenching of superoxide radical generated electrochemically.
引用
收藏
页码：1123 / 1127
页数：5
相关论文
共 50 条
  • [41] Copper(II), Zinc(II), and Cadmium(II) Formylbenzoate Complexes: Reactivity and Emission Properties
    Nath, Jitendra
    Tarai, Arup
    Baruah, Jubaraj B.
    ACS OMEGA, 2019, 4 (19): : 18444 - 18455
  • [42] Reactivity of 1-alkynylplatinum(II) complexes towards trialkylboranes
    Wrackmeyer, B
    Sebald, A
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1997, 544 (01) : 105 - 114
  • [43] ROLE OF THE LIGANDS ON THE REACTIVITY OF PLATINUM(II) COMPLEXES TOWARDS OXIDATION
    PELOSO, A
    GAZZETTA CHIMICA ITALIANA, 1988, 118 (11): : 787 - 791
  • [44] Reactivity of 1-alkynylplatinum(II) complexes towards trialkylboranes
    Wrackmeyer, B.
    Sebald, A.
    Journal of Organometallic Chemistry, 544 (01):
  • [45] SYNTHESIS, CHARACTERIZATION AND REACTIVITY PROPERTIES OF DIIRON DIAMIDE LIGAND COMPLEXES
    CARADONNA, JP
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1993, 205 : 446 - INOR
  • [46] MANGANESE(II) AND CHROMIUM(II) (QUESTIONABLE) PORPHYRIN COMPLEXES AND THEIR REACTIVITY TOWARDS DIOXYGEN
    YEE, S
    WONG, J
    KOUBA, J
    GONZALEZ, B
    REED, CA
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1976, : 51 - 51
  • [47] REACTION OF COPPER(II) CHLORIDE WITH 2,2'-BISBENZIMIDAZOLE IN ACETONE
    BRADY, JE
    FOGARTY, MA
    JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1971, 33 (08): : 2706 - &
  • [48] Reactivity of Dinuclear Copper(I)/pybox Complexes towards Isocyanides and Phosphanes
    Panera, Maria
    Diez, Josefina
    Merino, Isabel
    Rubio, Eduardo
    Pilar Gamasa, M.
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2011, (03) : 393 - 404
  • [49] Copper complexes of superpodal amine ligands and reactivity studies towards dioxygen
    Institut für Chemie, Technische Universität Berlin, Straße des 17. Juni 135, 10623 Berlin, Germany
    不详
    不详
    不详
    Eur. J. Inorg. Chem., 18 (3000-3013):
  • [50] Copper(I) tris(pyrazolyl)methane complexes and their reactivity towards dioxygen
    Cvetkovic, M
    Batten, SR
    Moubaraki, B
    Murray, KS
    Spiccia, L
    INORGANICA CHIMICA ACTA, 2001, 324 (1-2) : 131 - 140
12345