Copper(II)-Catalyzed Dehydrogenative Cross-Coupling between Two Azoles

被引:69
|
作者
Qin, Xurong
Feng, Boya
Dong, Jiaxing
Li, Xiaoyu
Xue, Ying
Lan, Jingbo [1 ]
You, Jingsong
机构
[1] Sichuan Univ, Coll Chem, Minist Educ, Key Lab Green Chem & Technol, Chengdu 610064, Peoples R China
来源
JOURNAL OF ORGANIC CHEMISTRY | 2012年 / 77卷 / 17期
关键词
C-H FUNCTIONALIZATION; CATALYZED ORTHO-ARYLATION; BOND FORMATION; SIMPLE ARENES; INDOLES; ALKENYLATION; HETEROCYCLES; ACTIVATIONS; MECHANISM; EFFICIENT;
D O I
10.1021/jo301128y
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The copper(II)-catalyzed dehydrogenative coupling between two different azoles for the preparation of unsymmetrical biazoles has been developed. The current catalytic system can effectively control the chemoselectivity for heterocoupling over homocoupling.
引用
收藏
页码:7677 / 7683
页数:7
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