Pentakis(trifluoromethyl)benzenediazonium Cation: A Useful Building Block for the Syntheis of Trifluoromethyl-Substituted Derivatives

被引：2
|
作者：
Kuett, Agnes [1 ]
Werner, Franz [2 ]
Kaljurand, Ivari [1 ]
Leito, Ivo [1 ]
Koppel, Ilmar A. [1 ]
机构：
[1] Univ Tartu, Inst Chem, EE-50411 Tartu, Estonia
[2] Tallinn Univ Technol, Dept Chem, EE-12618 Tallinn, Estonia
来源：
CHEMPLUSCHEM | 2013年 / 78卷 / 09期
关键词：
aromatic substitution; CC coupling; diazo compounds; fluorine; radical reactions; WALLED CARBON NANOTUBES; DIAZONIUM SALTS; ARENEDIAZONIUM IONS; ARYL RADICALS; AMINO-ACIDS; ARYLATION; F-18-FLUOROARYLATION; DIAZOTIZATION; REACTIVITY; VERSATILE;
D O I：
10.1002/cplu.201300160
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The sterically crowded, highly electron-deficient diazonium salt C 6(CF3)5N2+ BF 4- has been synthesized and sample dediazotization reactions were carried out. New compounds, C6(CF3) 5I, C6(CF3)5NO2, and C6(CF3)5NO were isolated and identified. Also, a more convenient route to C6(CF3)5NH 2 that gave good yield was achieved. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：932 / 936
页数：5
相关论文
共 50 条
  • [41] Conformational studies on heteroleptic trifluoromethyl-substituted phenylboranes
    Samigullin, Kamil
    Soltani, Yashar
    Lerner, Hans-Wolfram
    Wagner, Matthias
    Bolte, Michael
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2016, 72 : 189 - +
  • [42] Reactions of trifluoromethyl-substituted arylacetylenes with arenes in superacids
    Alkhafaji, H. M. H.
    Ryabukhin, D. S.
    Muzalevskiy, V. M.
    Osetrova, L. V.
    Vasilyev, A. V.
    Nenajdenko, V. G.
    RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2013, 49 (03) : 327 - 341
  • [43] TRIFLUOROMETHYL-SUBSTITUTED PYRIMIDINES FROM ENAMINES AND TRIFLUOROACETONITRILE
    BURGER, K
    WASSMUTH, U
    HEIN, F
    ROTTEGGER, S
    LIEBIGS ANNALEN DER CHEMIE, 1984, (05): : 991 - 1002
  • [44] BLENDS OF ALIPHATIC POLYAMIDES WITH A TRIFLUOROMETHYL-SUBSTITUTED POLYARAMIDE
    GARDLUND, ZG
    POLYMER, 1993, 34 (09) : 1850 - 1857
  • [45] Plasma polymerization of trifluoromethyl-substituted perfluorocyclohexane monomers
    Hynes, AM
    Shenton, MJ
    Badyal, JPS
    MACROMOLECULES, 1996, 29 (01) : 18 - 21
  • [46] Stereospecific synthesis of trifluoromethyl-substituted polyfunctionalized cyclopropanes
    Wang, Y
    Zhao, XM
    Li, YH
    Lu, L
    TETRAHEDRON LETTERS, 2004, 45 (41) : 7775 - 7777
  • [47] 1,1,1-TRIFLUORO-2-PENTEN-4-ONE AS A BUILDING BLOCK OF TRIFLUOROMETHYL-SUBSTITUTED COMPOUNDS
    OGOSHI, H
    MIZUSHIMA, H
    TOI, H
    AOYAMA, Y
    JOURNAL OF ORGANIC CHEMISTRY, 1986, 51 (12): : 2366 - 2368
  • [48] THE PREPARATION OF CERTAIN ETHERS OF TRIFLUOROMETHYL-SUBSTITUTED PHENOLS
    MCBEE, ET
    BOLT, RO
    GRAHAM, PJ
    TEBBE, RF
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1947, 69 (04) : 947 - 950
  • [49] Reactions of trifluoromethyl-substituted arylacetylenes with arenes in superacids
    H. M. H. Alkhafaji
    D. S. Ryabukhin
    V. M. Muzalevskiy
    L. V. Osetrova
    A. V. Vasilyev
    V. G. Nenajdenko
    Russian Journal of Organic Chemistry, 2013, 49 : 327 - 341
  • [50] PREPARATION AND PROPERTIES OF TRIFLUOROMETHYL-SUBSTITUTED AND TRIFLUOROMETHYLCHALCOGENYL-SUBSTITUTED ADAMANTANES
    FELDHOFF, R
    HAAS, A
    LIEB, M
    JOURNAL OF FLUORINE CHEMISTRY, 1994, 67 (03) : 245 - 251
12345