Pentakis(trifluoromethyl)benzenediazonium Cation: A Useful Building Block for the Syntheis of Trifluoromethyl-Substituted Derivatives

被引：2
|
作者：
Kuett, Agnes [1 ]
Werner, Franz [2 ]
Kaljurand, Ivari [1 ]
Leito, Ivo [1 ]
Koppel, Ilmar A. [1 ]
机构：
[1] Univ Tartu, Inst Chem, EE-50411 Tartu, Estonia
[2] Tallinn Univ Technol, Dept Chem, EE-12618 Tallinn, Estonia
来源：
CHEMPLUSCHEM | 2013年 / 78卷 / 09期
关键词：
aromatic substitution; CC coupling; diazo compounds; fluorine; radical reactions; WALLED CARBON NANOTUBES; DIAZONIUM SALTS; ARENEDIAZONIUM IONS; ARYL RADICALS; AMINO-ACIDS; ARYLATION; F-18-FLUOROARYLATION; DIAZOTIZATION; REACTIVITY; VERSATILE;
D O I：
10.1002/cplu.201300160
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The sterically crowded, highly electron-deficient diazonium salt C 6(CF3)5N2+ BF 4- has been synthesized and sample dediazotization reactions were carried out. New compounds, C6(CF3) 5I, C6(CF3)5NO2, and C6(CF3)5NO were isolated and identified. Also, a more convenient route to C6(CF3)5NH 2 that gave good yield was achieved. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：932 / 936
页数：5
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