Towards Lignin-Derived Chemicals Using Atom-Efficient Catalytic Routes

被引：25

作者：

Sudarsanam, Putla ^{[1
,2
]}

Ruijten, Dieter ^{[1
]}

Liao, Yuhe ^{[1
]}

Renders, Tom ^{[1
]}

Koelewijn, Steven-Friso ^{[1
]}

Sels, Bert F. ^{[1
]}

机构：

[1] Katholieke Univ Leuven, Fac Bioscience Engn, Ctr Sustainable Catalysis & Engn, Celestijnenlaan 200F, B-3001 Heverlee, Belgium

[2] CSIR, Natl Chem Lab, Catalysis & Inorgan Chem Div, Dr Homi Bhabha Rd, Pune 411008, Maharashtra, India

来源：

TRENDS IN CHEMISTRY | 2020年 / 2卷 / 10期

关键词：

ASSISTED SELECTIVE HYDRODEOXYGENATION; LIGNOCELLULOSE FRACTIONATION; PROMOTED DECARBOXYLATION; REDUCTIVE FRACTIONATION; RENEWABLE BISPHENOLS; PHENOLIC-COMPOUNDS; SHAPE SELECTIVITY; KRAFT LIGNIN; DEPOLYMERIZATION; BIOMASS;

D O I：

10.1016/j.trechm.2020.07.011

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Lignin is a potential non-fossil resource of diverse functionalized phenolic units. The most important lignin- derived monomers are 4-alkylphenols, 4- hydroxybenzaldehydes, 4-hydroxybenzoic acids, and 4-hydroxycinnamic acids/esters. Efficient transformation of lignin and/or its monomers into valuable aromatics and their derivatives is crucial, not only for a sustainable lignocellulose biorefinery, but also to reduce our dependence on fossil feedstocks. This review provides a concise account of the recent advances in lignocellulose fractionation/lignin depolymerization processes towards lignin-derived monomers. Subsequently, numerous potential atom-efficient catalytic routes for upgrading lignin monomers into drop-in chemicals and new polymer building blocks are discussed.

引用

页码：898 / 913

页数：16

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