Free energy of interaction of sodium dodecyl sulfate in aqueous solution with carbon black surfaces

被引：11

作者：

González-García, CM

González-Martín, ML ^{[1
]}

Gallardo-Moreno, AM

Gómez-Serrano, V

Labajos-Broncano, L

Bruque, JM

机构：

[1] Univ Extremadura, Dept Ingn Quim & Energet, E-06071 Badajoz, Spain

[2] Univ Extremadura, Dept Fis, E-06071 Badajoz, Spain

[3] Univ Extremadura, Dept Quim Inorgan, E-06071 Badajoz, Spain

来源：

JOURNAL OF COLLOID AND INTERFACE SCIENCE | 2002年 / 248卷 / 01期

关键词：

interfacial free energy; Langmuir equation; adsorption; surfactant; carbon blacks;

D O I：

10.1006/jcis.2001.8173

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The free energy of the adsorption process of an ionic surfactant from aqueous solutions onto a set of carbon blacks in the range of low concentrations was evaluated using the model proposed by van Oss and co-workers. The obtained results indicated that the free energy of interaction between adsorbent and adsorbate through water results mainly from Lifshitz-van der Waals and electrostatic interactions, and its value showed a good correspondence with that previously found from a combination of the classical measurements of adsorption isotherms and the Langmuir model. (C) 2002 Elsevier Science (USA).

引用

页码：13 / 18

页数：6

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