Copper-catalyzed synthesis of aryldiazo sulfones from arylhydrazines and sulfonyl chlorides under mild conditions

被引：13

作者：

Liu, Jin-Biao ^{[1
,2
]}

Chen, Fu-Jiao ^{[1
]}

Liu, En ^{[1
]}

Li, Jin-Hui ^{[1
]}

Qiu, Guanyinsheng ^{[3
]}

机构：

[1] Jiangxi Univ Sci & Technol, Sch Met & Chem Engn, Ganzhou 341000, Peoples R China

[2] Jiangxi Normal Univ, Minist Educ, Key Lab Funct Small Organ Mol, Nanchang 330022, Peoples R China

[3] Jiaxing Univ, Coll Biol Chem Sci & Engn, Jiaxing 314001, Peoples R China

来源：

NEW JOURNAL OF CHEMISTRY | 2015年 / 39卷 / 10期

关键词：

ARYLAZO ARYL SULFONES; TRANSITION-METAL-COMPLEXES; N'-TOSYL ARYLHYDRAZINES; THERMAL-DECOMPOSITION; DIAZONIUM SALTS; CONJUGATE BASES; AZO-COMPOUNDS; ARYLAZOSULFONES; ARYLATION; AZOXYSULFONES;

D O I：

10.1039/c5nj01760b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In this paper, aryldiazo sulfones are prepared from tandem sulfonylation/dehydrogenation reactions of arylhydrazines and sulfonyl chlorides. The transformations proceed well in the presence of catalytic CuSO4 center dot 5H(2)O, leading to aryldiazo sulfones in good to excellent yields. It is believed that this protocol represents a safe and convenient model for the synthesis of these versatile aryldiazo sulfones under mild conditions.

引用

页码：7773 / 7776

页数：4

共 50 条

[21] Copper-catalyzed oxidaive synthesis of alkenyl sulfones from alkenes with sodium sulfinates
Taniguchi, Nobukazu
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2012, 244
[22] Copper-catalyzed oxidative amidation between aldehydes and arylamines under mild conditions
Ding, Yongzheng
Zhang, Xian
Zhang, Dongyang
Chen, Yuting
Wu, Zhibing
Wang, Peiyi
Xue, Wei
Song, Baoan
Yang, Song
TETRAHEDRON LETTERS, 2015, 56 (06) : 831 - 833
[23] Aerobic Copper-Catalyzed Oxysulfonylation of Vinylarenes with Sodium Sulfinates under Mild Conditions: A Modular Synthesis of β-Ketosulfones
Rao, Wei-Hao
Gao, Chang
Jiang, Li-Li
Zhou, Fu-Yu
Liu, Jia-Fan
Zou, Guo-Dong
JOURNAL OF ORGANIC CHEMISTRY, 2024, 89 (17): : 12681 - 12692
[24] Copper-Catalyzed Nitration of Arylboronic Acids with Nitrite Salts Under Mild Conditions: An Efficient Synthesis of Nitroaromatics
Yan, Guobing
Zhang, Ling
Yu, Jian
LETTERS IN ORGANIC CHEMISTRY, 2012, 9 (02) : 133 - 137
[25] A microwave-assisted, copper-catalyzed three-component synthesis of dihydropyrimidinones under mild conditions
Pasunooti, Kalyan Kumar
Chai, Hua
Jensen, Chantel Nixon
Gorityala, Bala Kishan
Wang, Siming
Liu, Xue-Wei
TETRAHEDRON LETTERS, 2011, 52 (01) : 80 - 84
[26] Simple and efficient copper-catalyzed cascade synthesis of naphthols containing multifunctional groups under mild conditions
Xu, Hao
Li, Shangfu
Liu, Hongxia
Fu, Hua
Jiang, Yuyang
CHEMICAL COMMUNICATIONS, 2010, 46 (40) : 7617 - 7619
[27] Cu-Catalyzed Coupling of Sulfonyl Chlorides with Alkenes: Synthesis of Dienyl Sulfones and β-Chlorosulfones
Choudhary, Priyanka
Ranjan, Ravikant S.
Fernandes, Rodney A.
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2025, 28 (03)
[28] Copper-Catalyzed C-H Azidation of Anilines under Mild Conditions
Tang, Conghui
Jiao, Ning
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (46) : 18924 - 18927
[29] Copper-catalyzed multicomponent cascade synthesis of polyfunctionalized β-ketone sulfones
Luo, Chun-Mei
Sun, Yong-Bin
Wang, Ling-Tao
Dai, Nan-Nan
Li, Jiao-Zhe
Zhang, Jianfeng
Chen, Jin-Yang
Wei, Wen-Ting
Ge, Guo-Ping
ORGANIC CHEMISTRY FRONTIERS, 2023, 10 (16) : 4023 - 4029
[30] PALLADIUM CATALYZED CROSS-COUPLING OF ORGANOSTANNANES WITH SULFONYL CHLORIDES - A SIMPLE SYNTHESIS OF SULFONES
LABADIE, SS
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1988, 196 : 162 - ORGN

← 1 2 3 4 5 →