Dynamic structural conversion in a spin-crossover cobalt(II) compound with long alkyl chains

被引：72
|
作者：
Hayami, Shinya [1 ]
Murata, Kazuhisa [1 ]
Urakami, Daisuke [1 ]
Kojima, Yoshihiro [1 ]
Akita, Motoko [1 ]
Inoue, Katsuya [1 ,2 ]
机构：
[1] Hiroshima Univ, Grad Sch Sci, Dept Chem, Higashihiroshima 7398526, Japan
[2] Hiroshima Univ, Inst Adv Mat Res, Higashihiroshima 7398526, Japan
来源：
CHEMICAL COMMUNICATIONS | 2008年 / 48期
关键词：
D O I：
10.1039/b814415j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A cobalt(II) compound [Co(C14-terpy)(2)](BF4)(2)center dot MeOH (1) with long alkyl chains was prepared, and exhibited unique SCO at T(1) = 50 K and spin transition at T(2)up arrow = 206 K and T(2)down arrow = 184 K with hysteresis (Delta T = 22 K) accompanying the motion of the long alkyl chains.
引用
收藏
页码：6510 / 6512
页数：3
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