Synthesis and axial-ligand binding of zinc complexes of amphiphilic porphyrins containing a hydrophobic binding pocket

被引:4
|
作者
Imai, H
Munakata, H
Takahashi, A
Nakagawa, S
Uemori, Y
机构
[1] Faculty of Pharmaceutical Sciences, Hokuriku University, Kanazawa 920-11
关键词
D O I
10.1246/cl.1997.819
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Amphiphilic zinc porphyrins containing two sulfonate groups and a hydrophobic binding pocket were synthesized efficiently and characterized. Binding of pyridine, butylamine, and pyrrolidine to the zinc complexes was examined spectrophotometrically in water and in chloroform. The binding behavior was discussed on the basis of the binding constants.
引用
收藏
页码:819 / 820
页数:2
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