One-color spectroscopy of threshold electrons produced in pulsed ionization of high-lying rydberg states of naphthalene by an electric field

被引:0
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作者
Akopyan, ME [1 ]
Ivanov, VS [1 ]
Kleimenov, VI [1 ]
Feofilov, AG [1 ]
机构
[1] St Petersburg State Univ, Inst Phys, St Petersburg 198904, Russia
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O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
In a one-color spectrum of threshold electrons produced in pulsed ionization of long-lived (0.1-1.0 mu s) Rydberg states of naphthalene by an electric field, a new group of electrons was observed. It was attributed to the two-step excitation of high-lying Rydberg states of a molecule, which converge to the first excited electronic state of a cation. A refined value of the second adiabatic ionization energy of naphthalene was obtained (8.913 +/- 0.004 eV).
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页码:877 / 880
页数:4
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