One-pot synthesis of β- and γ-aminofunctionalised amines and silanes via hydroaminomethylation of enamines and vinylsilanes

被引：15
|
作者：
Bärfacker, L [1 ]
Rische, T [1 ]
Eilbracht, P [1 ]
机构：
[1] Univ Dortmund, D-44221 Dortmund, Germany
来源：
TETRAHEDRON | 1999年 / 55卷 / 23期
关键词：
hydroaminomethylation; rhodium(I)-catalysis; beta- and gamma-aminofunctionalised amines; enamines; vinylsilanes;
D O I：
10.1016/S0040-4020(99)00350-6
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Heterofunctionalised enamines and vinylsilanes under hydroformylation conditions in the presence of primary or secondary amines are converted to form diamines or aminosilanes in one step. This selective one-pot hydroaminomethylation procedure establishes an easy and convenient access to beta- and gamma-aminofunctionalised amines and silanes with potential biological activity. (C) 1999 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：7177 / 7190
页数：14
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