Kinetics of liquid-phase methanol synthesis over Cu/ZnO/MnO3/Al2O3 catalyst

被引：0
|
作者：
Nowicki, L [1 ]
机构：
[1] Politechn Lodzka, Wydzial Inzynierii Procesowej & Ochrony Srodowisk, PL-90924 Lodz, Poland
来源：
INZYNIERIA CHEMICZNA I PROCESOWA | 2002年 / 23卷 / 01期
关键词：
D O I：
暂无
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
A mathematical model was developed to describe kinetics of the low-pressure methanol synthesis from syngas over Polish commercial Cu/ZnO/MnO3/Al2O3 (BT-1) catalyst. A rigorous reaction network including methanol formation from CO and CO2 and the water gas-shift reaction was a basis for the derivation of the rate expressions. The kinetic parameters were estimated by nonlinear regression of the experimental data obtained in a stirred tank slurry reactor. Model simulation showed that under reaction conditions, methanol is formed mainly from CO2.
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页码：83 / 98
页数：16
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