Evidence for a new nitrosyl-to-nitro reaction and an acetamide formation in the {RuNO}6-type complex, cis-[Ru(NO)(CH3CN)(bpy)2]3+

被引：19
|
作者：
Nagao, H [1 ]
Ito, K [1 ]
Tsuboya, N [1 ]
Ooyama, D [1 ]
Nagao, N [1 ]
Howell, FS [1 ]
Mukaida, M [1 ]
机构：
[1] Sophia Univ, Fac Sci & Engn, Dept Chem, Chiyoda Ku, Tokyo 1028554, Japan
来源：
INORGANICA CHIMICA ACTA | 1999年 / 290卷 / 01期
关键词：
crystal structures; ruthenium complexes; nitrosyl complexes; acetamide complexes;
D O I：
10.1016/S0020-1693(99)00094-8
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction between cis-[Ru(NO)(CH3CN)(bpy)(2)](3+) and a free NO2- gives an appreciable amount of the nitro species cis-[Ru(NO2)(CH3CN)(bpy)(2)](+). Although definitive evidence for the mechanistic illustration of the nitrosyl-to-nitro conversion is still unavailable, an oxide abstraction from NO2- to the nitrosyl ligand appears to be the key reaction. In addition, cis-[Ru(NO)(CH3C(O)NH)(bpy)(2)](2+) having an acetamide ligand is formed during the reaction. The structure of the complex, used as a starting material of the present reaction, was determined by single-crystal X-ray diffraction methods; for cis-[Ru(NO)(CH3CN)(bpy)(2)](ClO4)(3). CH3CN: FW = 823.91, monoclinic, P2(1)/n, a = 12.471(3), b = 15.041(7), c = 17.598(4) Angstrom, beta = 94.65(2)degrees, V = 3289(1) Angstrom(3), Z = 4, R = 0.081, R-w = 0.050. (C) 1999 Elsevier Science S.A. All rights reserved.
引用
收藏
页码：113 / 119
页数：7
相关论文
共 50 条
  • [31] Reactivity of coordinated nitriles -: Formation of the acetamidine complex cis-[(PMe3)2Pt{1-MeTy(-H)}{CH3C(NH)NH2}]+ from the 1-methylthyminate compound cis-[(PMe3)2Pt{1-MeTy(-H)}(CH3CN)]+ -: Synthesis, characterisation, and X-ray structures
    Longato, B
    Bandoli, G
    Mucci, A
    Schenetti, L
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2001, (12) : 3021 - 3029
  • [32] Crystal and molecular structure of [Ru(bpy)2(2,3-dpp)]Cl2 · 3H2O · CH3CN and 1H and 99Ru NMR spectra of [Ru(bpy)2(2,n-dpp)] [PF6]2 (bpy = 2,2′-bipyridine, dpp = bis(2-pyridyl)pyrazine, n = 3 or 5)
    Ferrari, Marisa Belicchi
    Fava, Giovanna Gasparri
    Pelosi, Giorgio
    Predieri, Giovanni
    Vignali, Carlo
    Denti, Gianfranco
    Serroni, Scolastica
    Inorganica Chimica Acta, 1998, 275-276 : 320 - 326
  • [33] Crystal and molecular structure of [Ru(bpy)2(2,3-dpp)]Cl2•3H2O•CH3CN and 1H and 99Ru NMR spectra of [Ru(bpy)2(2,n-dpp)][PF6]2 (bpy = 2,2′-bipyridine, dpp = bis(2-pyridyl)pyrazine, n = 3 or 5)
    Ferrari, MB
    Fava, GG
    Pelosi, G
    Predieri, G
    Vignali, C
    Denti, G
    Serroni, S
    INORGANICA CHIMICA ACTA, 1998, 276 (1-2) : 320 - 326
  • [34] The reaction of ferrocenyl acetylene with [RuCp(PR3)(CH3CN)2]PF6 (R = Me, Ph, Cy).: Formation of the first allenyl carbene complexes
    Rüba, E
    Mereiter, K
    Schmid, R
    Kirchner, K
    Schottenberger, H
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2001, 637 : 70 - 74
  • [35] Synthesis, properties and molecular structure of [Ru(tpm)(bpy) (CH3CN)](PF6)2 (tpm = tris(1-pyrazolyl)methane, bpy=2,2′-bipyridine) -: Another example of nitrile hydrolysis promoted by Ruthenium(II)
    Katz, NE
    Fagalde, F
    de Katz, NDL
    Mellace, MG
    Romero, I
    Llobet, A
    Benet-Buchholz, J
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2005, (15) : 3019 - 3023
  • [36] A new type of supramolecular assembly consisting of crown ether complex cation and a polyoxometalate anion:: Synthesis and crystal structure of [Na(C20H24O6)(CH3CN)2]2[MO6O19] • 4CH3CN
    Shivaiah, Vaddypally
    INORGANIC CHEMISTRY COMMUNICATIONS, 2006, 9 (12) : 1191 - 1194
  • [37] Synthesis of a Naphthalene-Bridged Bis(guanidinato)ytterbium(II) Complex and an Unexpected Pathway in Its Reaction with CH3CN, p-CIC6H4CH2CN, and Ph2CHCN
    Wang, Chuanyong
    Zhang, Xingmin
    Xue, Mingqiang
    Zhang, Yong
    Shen, Qi
    ORGANOMETALLICS, 2013, 32 (13) : 3618 - 3624
  • [38] HYDROGENATION OF CARBON-DIOXIDE TO FORMIC-ACID USING A 6,6'-DICHLORO-2,2'-BIPYRIDINE COMPLEX OF RUTHENIUM, CIS-[RU(6,6'-CL(2)BPY)(2)(H2O)(2)](CF3SO3)(2)
    LAU, CP
    CHEN, YZ
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1995, 101 (01) : 33 - 36
  • [39] Synthcsis, Structure and Magnetochemistry of a New Hexanuclear Manganese Oxide Complex of the Formula [Mn6O2 (O2CPh)10(CH3CN)4]
    Jin AN
    Zhi Da CHEN
    Jiang BIAN
    Shi Xi WANG
    Guang Xian XU (Department of Chemistry
    Chinese Chemical Letters, 1999, (08) : 697 - 700
  • [40] Synthesis, structure and magnetochemistry of a new hexanuclear manganese oxide complex of the formula [Mn6O2 (O2CPh)10 (CH3CN)4]
    An, J
    Da Chen, Z
    Bian, J
    Wang, SX
    Xu, GX
    CHINESE CHEMICAL LETTERS, 1999, 10 (08) : 697 - 700
12345