Conductometric study of sodium dodecyl sulfate-nonionic surfactant (Triton X-100, Tween 20, Tween 60, Tween 80 or Tween 85) mixed micelles in aqueous solution

被引：53
|
作者：
Cirin, Dejan M. [1 ]
Posa, Mihalj M. [1 ]
Krstonosic, Veljko S. [1 ]
Milanovic, Maja Lj [1 ]
机构：
[1] Univ Novi Sad, Fac Med, Dept Pharm, Novi Sad 21000, Serbia
来源：
HEMIJSKA INDUSTRIJA | 2012年 / 66卷 / 01期
关键词：
Conductometric study; mixed micelles; cmc; anionic surfactant; SDS; nonionic surfactants; Triton X-100; Tween; BINARY-MIXTURES; LAURYL SULFATE; SYNERGISM; MICELLIZATION; MECHANISM; BEHAVIOR; SYSTEMS; VIRUSES;
D O I：
10.2298/HEMIND110612059C
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
The present study is concerned with the determination of the critical micelle concentration (cmc) of mixed micelles of sodium dodecyl sulfate with one of five nonionic surfactants (Triton X-100, Tween 20, Tween 60, Tween 80 or Tween 85) from conductance measurements. Based on the calculated values of the beta parameter we have noticed that SDS-nonionic surfactants mostly showed strong synergistic effects. It was found that nonionic surfactants with mainly longer and more hydrophobic tails show stronger interactions with hydrophobic parts of SOS, thus expressing stronger synergism. The strongest synergistic effect was noticed in an SDS-Tween 80 binary system. The SDS-Tween 85 micellar system showed antagonistic effect, most probably because the presence of the double bond in its three hydrophobic tails (three C18 tails) makes it sterically rigid.
引用
收藏
页码：21 / 28
页数：8
相关论文
共 50 条
  • [31] Modulation of the Photophysical Properties of Curcumin in Nonionic Surfactant (Tween-20) Forming Micelles and Niosomes: A Comparative Study of Different Microenvironments
    Mandal, Sarthak
    Banerjee, Chiranjib
    Ghosh, Surajit
    Kuchlyan, Jagannath
    Sarkar, Nilmoni
    JOURNAL OF PHYSICAL CHEMISTRY B, 2013, 117 (23): : 6957 - 6968
  • [32] Sodium dodecyl sulfate - Tween 20 mixed micellar electrokinetic chromatography for separation of hydrophobic cations: Application to adrenaline and its precursors
    Esaka, Y
    Tanaka, K
    Uno, B
    Goto, M
    Kano, K
    ANALYTICAL CHEMISTRY, 1997, 69 (07) : 1332 - 1338
  • [33] Promotion of clinoptilolite adsorption for azithromycin antibiotic by Tween 80 and Triton X-100 surface modifiers under batch and fixed-bed processes
    Saadi, Zahra
    Fazaeli, Reza
    Vafajoo, Leila
    Naser, Iraj
    Mohammadi, Ghodratollah
    CHEMICAL ENGINEERING COMMUNICATIONS, 2021, 208 (03) : 328 - 348
  • [34] Binary mixed micelles of polysorbates (Tween 20 and Tween 60) and bile salts (Na-hyodeoxycholate and Na-cholate): Regular solution theory and change of pKa values of micellar bile acid - a novel approach to estimate of the stability of the mixed micelles
    Posa, Mihalj
    Popovic, Kosta
    Cirin, Dejan
    Farkas, Zita
    FLUID PHASE EQUILIBRIA, 2015, 396 : 1 - 8
  • [35] Properties of aqueous solutions of nonionic surfactants, Triton X-114 and Tween 80, at temperatures from 293 to 318 K: Spectroscopic and ultrasonic studies
    Szymczyk, Katarzyna
    Taraba, Anna
    CHEMICAL PHYSICS, 2017, 483 : 96 - 102
  • [36] Effect of microheterogeneous environments of CTAB, Triton X-100, and Tween 20 on the oxidative degradation of D-fructose by nanoparticles of MnO2
    Midya, Jayanta K.
    Ghosh, Dinesh C.
    Pal, Biswajit
    Sen, Pratik K.
    INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 2019, 51 (03) : 149 - 160
  • [37] Degradation of trichloroethylene in aqueous solution by sodium percarbonate activated with Fe(II)-citric acid complex in the presence of surfactant Tween-80
    Lyu, Yanchen
    Lyu, Shuguang
    Tang, Ping
    Jiang, Wenchao
    Sun, Yong
    Li, Ming
    Sui, Qian
    CHEMOSPHERE, 2020, 257 (257)
  • [38] Interfacial and micellization behaviors of binary and ternary mixtures of amphiphiles (Tween-20, Brij-35, and sodium dodecyl sulfate) in aqueous medium
    Ghosh, S
    Moulik, SP
    JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1998, 208 (02) : 357 - 366
  • [39] Interfacial and micellization behaviors of binary and ternary mixtures of amphiphiles (Tween-20, Brij-35, and sodium dodecyl sulfate) in aqueous medium
    J Colloid Interface Sci, 2 (357):
  • [40] Interaction mode of hydroxypropyl-β-cyclodextrin with vaccine adjuvant components Tween 80 and Triton X-100 revealed by fluorescence increasing-quenching analysis
    Kurosawa, Yuya
    Goto, Satoru
    Mitsuya, Kengo
    Otsuka, Yuta
    Yokoyama, Hideshi
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2023, 25 (08) : 6203 - 6213
12345