Selective oxidation of H2S in the presence of ammonia and water using Co3O4/SiO2 catalyst

被引:14
|
作者
Chun, SW [1 ]
Jang, JY [1 ]
Park, DW [1 ]
Woo, HC [1 ]
Chung, JS [1 ]
机构
[1] PUSAN NATL UNIV,DEPT CHEM ENGN,PUSAN 609735,SOUTH KOREA
关键词
selective oxidation; hydrogen sulfide; ammonia; water; catalyst;
D O I
10.1007/BF02706099
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The catalytic performance of some metal oxides in the selective oxidation of H2S in the stream containing water Vapor and ammonia was investigated in this study. Among the catalysts tested, Co3O4/SiO2 was the most promising catalyst for practical application. It showed very small amount of SO2 emission even in the presence of excess water and ammonia. The solid product formed in the reaction was a mixture of elemental sulfur, ammonium thiosulfate and ammonium sulfate.
引用
收藏
页码:216 / 218
页数:3
相关论文
共 50 条
  • [31] Oxidation of octadecanol to octadecanoic acid over Cr2O3-Co3O4/SiO2 catalyst
    Zhuang, H
    Bi, YL
    Cheng, TX
    Liu, Y
    Zhou, GD
    Li, WX
    Zhen, KJ
    CHINESE JOURNAL OF CATALYSIS, 2003, 24 (02) : 115 - 118
  • [32] Selective oxidation of H2S to elemental sulfur over TiO2/SiO2 catalysts
    Chun, SW
    Jang, JY
    Park, DW
    Woo, HC
    Chung, JS
    APPLIED CATALYSIS B-ENVIRONMENTAL, 1998, 16 (03) : 235 - 243
  • [33] Selective oxidation of H2S over the LaCoO3 catalyst
    Yu, Xin-Lei
    Pan, Wei-Tong
    Gao, Rui
    Gao, De-Zhi
    Liu, Xia
    Dai, Zheng-Hua
    Yu, Guang-Suo
    Wang, Fu-Chen
    Ranliao Huaxue Xuebao/Journal of Fuel Chemistry and Technology, 2019, 47 (08): : 973 - 979
  • [34] Enhancing catalytic CH4 oxidation over Co3O4/SiO2 core-shell catalyst by substituting Co2+ with Mn2+
    Wang, Haiwang
    Li, Jinlong
    Liu, Wenge
    Xu, Xin
    Wei, Xinfang
    Chao, Li
    Zhao, Ruifeng
    Qi, Xiwei
    Che, Ling
    JOURNAL OF DISPERSION SCIENCE AND TECHNOLOGY, 2021, 42 (01) : 82 - 92
  • [35] Solution-processed rapid synthesis strategy of Co3O4 for the sensitive and selective detection of H2S
    Navale, S. T.
    Liu, Chenshitao
    Gaikar, P. S.
    Patil, V. B.
    Sagar, R. U. R.
    Du, B.
    Mane, R. S.
    Stadler, F. J.
    SENSORS AND ACTUATORS B-CHEMICAL, 2017, 245 : 524 - 532
  • [36] Hierarchically structured Co3O4/SiO2 composites by Co nanocrystals transformation
    Wu, Si-Ming
    Wang, Yi-Tian
    Jiang, Nan
    Xiao, Shi-Tian
    Shi, Jia-Xin
    Wan, Ying
    Luo, Zhi-Qiang
    Yang, Xiao-Yu
    CHEMICAL PHYSICS LETTERS, 2020, 740
  • [37] Asphaltene adsorption of Co3O4 nanoparticles modified by SiO2 film
    Wang, Tianguan
    Zhong, Xiankang
    Zhang, Zhi
    Yuan, Xi
    Zhou, Li
    Zheng, Ziqi
    Farhadian, Abdolreza
    Hu, Junying
    APPLIED SURFACE SCIENCE, 2022, 602
  • [38] Catalytic Effect of SiO2/Co3O4 Core-Shell Catalyst on Thermal Decomposition of AP
    Yin Ping
    Jiang Xiao-Hong
    Zou Min
    Lu Lu-De
    Wang Xin
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2014, 30 (01) : 185 - 191
  • [39] Selective catalytic oxidation of H2S over V2O5 supported on TiO2-pillared clay catalysts in the presence of water and ammonia
    Bineesh, Kanattukara Vijayan
    Kim, Dong-Kyu
    Kim, Moon-Il
    Park, Dae-Won
    APPLIED CLAY SCIENCE, 2011, 53 (02) : 204 - 211
  • [40] Hydrogenation of 1,3-butadiene on Pd/SiO2 in the presence of H2S -: Deactivation and reactivation of the catalyst
    Rodriguez, JC
    Santamaria, J
    Monzon, A
    APPLIED CATALYSIS A-GENERAL, 1997, 165 (1-2) : 147 - 157