A new acentric borate of K2Ba[B4O5(OH)4]2•10H2O: synthesis, structure and nonlinear optical property

被引：5
|
作者：
Lin, Feng [1 ,2 ]
Dong, Yaping [1 ]
Peng, Jiaoyu [1 ]
Wang, Liping [1 ,2 ]
Li, Wu [1 ]
Yang, Bo [1 ]
机构：
[1] Chinese Acad Sci, Qinghai Inst Salt Lakes, Salt Lake Comprehens Utilizat Resources Engn Tech, Xining, Peoples R China
[2] Univ Chinese Acad Sci, Beijing, Peoples R China
来源：
PHASE TRANSITIONS | 2016年 / 89卷 / 10期
基金：
中国国家自然科学基金;
关键词：
slow evaporation method; nonlinear optical; hydrate borate; CRYSTAL-STRUCTURE; BARIUM BORATE;
D O I：
10.1080/01411594.2015.1124273
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
A new acentric mixed metal borate of composition K2Ba[B4O5(OH)(4)](2)10H(2)O, has been successfully obtained by slow evaporation solution method. The compound crystallizes in the Orthorhombic space group Pna21 (No.33) with a = 16.8668(7) angstrom, b = 13.0903(5) angstrom, c = 11.5529(5) angstrom and Z = 4. [B4O5(OH)(4)](2-) clusters serve as fundamental building unit linking with BaO8, K1O(6), K2O(7) by common O atoms to form three-dimensional layer structure. The second harmonic generation measurements in the powder samples reveal that the compound exhibits approximately 0.5times that of KH2PO4 (KDP) and phase matching.
引用
收藏
页码：996 / 1005
页数：10
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