Synthesis, structure, and properties of a novel hydrated borate Rb4[B4O5(OH)4]2•3H2O

被引：11

作者：

Zhao, Yi ^{[1
,2
]}

Pan, Shilie ^{[1
]}

Li, Feng ^{[1
]}

Wang, Yongjiang ^{[1
]}

Fan, Xiaoyun ^{[1
]}

Dong, Xiaoyu ^{[1
]}

Jia, Dianzeng ^{[2
]}

Guo, Jixi ^{[2
]}

Zhou, Zhongxiang ^{[1
]}

机构：

[1] Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China

[2] Xinjiang Univ, Coll Chem & Chem Engn, Urumqi 830046, Peoples R China

来源：

SOLID STATE SCIENCES | 2011年 / 13卷 / 01期

基金：

中国国家自然科学基金;

关键词：

Rb-4[B4O5(OH)(4)](2)center dot 3H(2)O; Borate; Crystal structure; Crystal growth; NONLINEAR-OPTICAL CRYSTAL; THERMAL-BEHAVIOR; RUBIDIUM PENTABORATE; GROWTH; TETRAHYDRATE; REFINEMENT; CS; RB; TL;

D O I：

10.1016/j.solidstatesciences.2010.10.013

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Rb-4[B4O5(OH)(4)]2 center dot 3H(2)O has been grown by slow evaporation method with crystal sizes up to 11 mm x 7 mm x 4 mm. Its crystal structure has been determined by single-crystal X-ray diffraction and further characterized by powder X-ray diffraction (XRD). IR, and TGA. It crystallizes in the orthorhombic space group Pbcn, with a = 16.3984(14) angstrom, b = 7.7850(7) angstrom, c = 16.0763(16) angstrom, and Z = 4. It contains isolated [B4O5(OH)(4)](2-) polyanions, free water molecules and Rb cations. The Rb(1) and Rb(2) atoms are coordinated by nine and ten oxygen atoms, respectively. Connections between isolated [B4O5(OH)(4)](2-) polyanions are provided by Rb polyhedra and the hydrogen-bonding to form a three-dimensional network. (C) 2010 Elsevier Masson SAS. All rights reserved.

引用

页码：82 / 87

页数：6

共 50 条

[1] Thermodynamic properties of Cs2[B4O5(OH)4] • 3H2O
Liu, ZH
Li, SY
Hu, MC
JOURNAL OF CHEMICAL THERMODYNAMICS, 2005, 37 (09): : 1003 - 1006
[2] MECHANOCHEMICAL SYNTHESIS OF TINCALCONITS NA2[B4O5(OH)4].3H2O
KOLOSOV, AS
KORMILITSINA, ZA
AVVAKUMOV, EG
IZVESTIYA SIBIRSKOGO OTDELENIYA AKADEMII NAUK SSSR SERIYA KHIMICHESKIKH NAUK, 1989, (06): : 123 - 130
[3] Crystal structure and thermal behavior of Cs2[B4O5(OH)4]3H2O
Touboul, M
Penin, N
Nowogrocki, G
JOURNAL OF SOLID STATE CHEMISTRY, 1999, 143 (02) : 260 - 265
[4] Crystal growth, thermal and linear optical properties of the non-centrosymmetric hydrated tetraborates Na2[B4O5(OH)4] • 3H2O (tincalconite) and K2[B4O5(OH)4] • 2H2O
Hellwig, H
Becker, P
Ahrweiler, S
Bohaty, L
CRYSTAL RESEARCH AND TECHNOLOGY, 2000, 35 (10) : 1151 - 1161
[5] K2[B4O5(OH)4]•H2O and K2[B4O5(OH)4]: two new hydrated potassium borates with isolated [B4O5(OH)4]2- units and different structural frameworks
Shi, Tingting
Zhang, Fangfang
Tudi, Abudukadi
Yang, Zhihua
Pan, Shilie
NEW JOURNAL OF CHEMISTRY, 2019, 43 (29) : 11660 - 11665
[6] Na4Ca[B4O5(OH)4]3·14H2O: An Acentric Supramolecular Framework Borate Based on [B4O5(OH)4]2− Cluster Units
Chong-An Chen
Qi Wei
Bai-Feng Yang
Guo-Yu Yang
Journal of Cluster Science, 2017, 28 : 2157 - 2165
[7] Synthesis, Crystal Structure and Thermal Behavior of Co(en)3[B4O5(OH)4]Cl•3H2O and [Ni(en)3][B5O6(OH)4]2•2H2O
Zheng Lijuan
Zhang Jianjian
Liu Zhihong
CHINESE JOURNAL OF CHEMISTRY, 2009, 27 (03) : 494 - 500
[8] Synthesis, characterization and thermodynamic properties of NaCs[B4O5(OH)4]•4H2O
Zhao, Fengying
Zhou, Jianguo
Yang, Qian
Yang, Lin
Song, Shili
Xia, Shuping
Gao, Shiyang
THERMOCHIMICA ACTA, 2009, 483 (1-2) : 70 - 72
[9] Na4Ca[B4O5(OH)4]3•14H2O: An Acentric Supramolecular Framework Borate Based on [B4O5(OH)4]2- Cluster Units
Chen, Chong-An
Wei, Qi
Yang, Bai-Feng
Yang, Guo-Yu
JOURNAL OF CLUSTER SCIENCE, 2017, 28 (04) : 2157 - 2165
[10] Crystal structure and thermal behavior of Rb2[B4O5(OH)4]•3.6H2O
Touboul, M
Penin, N
Nowogrocki, G
JOURNAL OF SOLID STATE CHEMISTRY, 2000, 149 (01) : 197 - 202

← 1 2 3 4 5 →