Post-Modification of the Interior of Porous Shape-Persistent Organic Cage Compounds

被引：133

作者：

Schneider, Markus W. ^{[1
]}

Oppel, Iris M. ^{[2
]}

Griffin, Alexandra ^{[3
]}

Mastalerz, Michael ^{[1
]}

机构：

[1] Univ Ulm, Inst Organ Chem & Adv Mat 2, D-89081 Ulm, Germany

[2] Rhein Westfal TH Aachen, Dept Inorgan Chem, D-52056 Aachen, Germany

[3] Oxford Diffract Agilent Technol, Yarnton, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 13期

关键词：

cage compounds; gas sorption; porous materials; post-synthetic modification; supramolecular chemistry; DISCRETE; CRYSTAL; FUNCTIONALIZATION; MOLECULES; NITROGEN;

D O I：

10.1002/anie.201208156

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Interior decorating: A post-synthetic method allows porous organic cage compounds to be prepared with functionalized interior cavities. The approach produces modified cage compounds in quantitative yield and opens the possibility of preparing organic alloys with different functionality. The solution-based technique shows the advantage of solubility, an inherent property of porous materials derived from discrete organic molecules. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：3611 / 3615

页数：5

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