A 1D double chains architecture based on the pyridine-2-sulfonate, 4,4′-Bipyridine and acetate-bridged of Zn(II) complex: Synthesis, spectral, thermal properties, and crystal structure

被引：3
|
作者：
Shi, Z. F. [1 ]
Li, J. M. [1 ]
He, K. H. [1 ]
Jiang, Y. M. [2 ]
机构：
[1] Qinzhou Univ, Coll Chem & Chem Engn, Qinzhou 535000, Guangxi, Peoples R China
[2] Guangxi Normal Univ Guilin, Coll Chem & Chem Engn, Guangxi 541004, Peoples R China
来源：
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2012年 / 38卷 / 09期
关键词：
HYDROTHERMAL SYNTHESIS; 5-SULFOISOPHTHALIC ACID; NETWORK STRUCTURE; 3D NETWORK; CHEMISTRY; SOLIDS;
D O I：
10.1134/S1070328412080064
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new 1D double chains Zn(II) supramolecule framework, {[Zn-2(2-pSO(3))(2)(Ac)(2)(4,4'-Bipy)(2)](4,4'-Bipy)} (n) (I) (2-pSO(3)H = pyridine-2-sulfonate, 4,4'-Bipy = 4,4'-bipyridine), was synthesized by reaction of Zn(CH3COO)(2) center dot 2H(2)O in methanol-water mixed solution and characterized by X-ray diffraction, elemental analysis, and IR spectrum. X-ray analysis indicates that I is a coordination polymer in which two deprotonated 2-pSO(3)H through the aromatic nitrogens in trans positions, oxygens in cis positions and two N atoms of 4,4'-Bipy and two mu(2)-Ac- ligands, resulting in a ZnN3O3 distorted octahedral geometry. The 1D coordination polymer was connected to 2D and 3D supramolecule framework via pi-stacking and weak C-HaEuro broken vertical bar O contacts. The complex I also displays strong fluorescence property and good thermal stability.
引用
收藏
页码：614 / 619
页数：6
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