Oxygen Reduction at Very Low Overpotential on Nanoporous Ag Catalysts

被引:81
|
作者
Zhou, Yang [1 ]
Lu, Qi [2 ,3 ]
Zhuang, Zhongbin [3 ]
Hutchings, Gregory S. [3 ]
Kattel, Shyam [4 ]
Yan, Yushan
Chen, Jingguang G. [2 ,4 ]
Xiao, John Q. [1 ]
Jiao, Feng
机构
[1] Univ Delaware, Dept Phys & Astron, Newark, DE 19716 USA
[2] Columbia Univ, Dept Chem Engn, New York, NY 10027 USA
[3] Univ Delaware, Dept Chem & Biomol Engn, Newark, DE 19716 USA
[4] Brookhaven Natl Lab, Dept Chem, Upton, NY 11973 USA
基金
美国国家科学基金会;
关键词
MEMBRANE FUEL-CELLS; SILVER NANOWIRES; AIR BATTERIES; CARBON; ELECTROCATALYSTS; ELECTROREDUCTION; HYDROXIDE; OXIDATION;
D O I
10.1002/aenm.201500149
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A monolithic nanoporous silver catalyst is developed to achieve a better performance than platinum at very low overpotentials for oxygen reduction reaction in alkaline conditions. Benefiting from the reaction-promoting electrode architecture and the enhanced surface area, such a nanoporous silver catalyst exhibits a threefold improved overall activity compared to that of commercial state-of-the-art platinum carbon catalysts at 0.90 V versus RHE. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
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页数:4
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