A cobalt-free perovskite-type La0.6Sr0.4Fe0.9Cr0.1O3-α cathode for proton-conducting intermediate temperature solid oxide fuel cells

被引：29
|
作者：
Ding, Zuolong [1 ]
Yang, Zhijie [1 ]
Zhao, Dongmei [1 ]
Deng, Xuli [1 ]
Ma, Guilin [1 ]
机构：
[1] Soochow Univ, Coll Chem Chem Engn & Mat Sci, Key Lab Organ Synth Jiangsu Prov, Suzhou 215123, Peoples R China
来源：
JOURNAL OF ALLOYS AND COMPOUNDS | 2013年 / 550卷
基金：
中国国家自然科学基金;
关键词：
Cobalt-free; Perovskite-type; Proton-conducting IT-SOFC; Conductivities; Membrane; COMPOSITE CATHODES; ELECTROLYTE; OPTIMIZATION; PERFORMANCE; PERMEATION; MEMBRANES; SOFCS;
D O I：
10.1016/j.jallcom.2012.09.107
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A cobalt-free perovskite-type cathode material La0.6Sr0.4Fe0.9Cr0.1O3-alpha (LSFC10) was prepared by a citric acid-nitrate process and investigated as a potential cathode material for proton-conducting intermediate-temperature solid oxide fuel cells (IT-SOFCs). The maximum conductivity of LSFC10 reached 138 S cm(-1) under oxygen at 550 degrees C. A Ni-BZCY composite anode-supported proton-conducting BaZr0.1Ce0.7Y0.2O3-alpha (BZCY) electrolyte membrane was successfully fabricated by a simple, cost-effective spin coating process. The peak power densities of the H-2/O-2 fuel cell using BZCY electrolyte membrane, Ni-BZCY composite anode and LSFC10 cathode reached 412 mW cm(-2), and the interfacial polarization resistance for the fuel cell was as low as 0.19 Omega cm(2) under open circuit conditions, at 700 degrees C. These results reveal LSFC10 is a suitable cathode material for proton-conducting IT-SOFCs. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码：204 / 208
页数：5
相关论文
共 50 条
  • [21] Evaluation of La0.6Sr0.4Co0.2Fe0.8O3-δ as a Potential Cathode for Proton-Conducting Solid Oxide Fuel Cell
    Ismail, Ismariza
    Osman, Nafisah
    Jani, Abdul Mutalib Md
    SAINS MALAYSIANA, 2018, 47 (02): : 387 - 391
  • [22] A new cobalt-free composite cathode Pr0.6Sr0.4Cu0.2Fe0.8O3-δ-Ce0.8Sm0.2O2-δ for proton-conducting solid oxide fuel cells
    Gong, Zheng
    Hou, Jie
    Wang, Zhongtao
    Cao, Jiafeng
    Zhang, Junyu
    Liu, Wei
    ELECTROCHIMICA ACTA, 2015, 178 : 60 - 64
  • [23] Production of La0.6Sr0.4Co0.2Fe0.8O3-δ cathode with graded porosity for improving proton-conducting solid oxide fuel cells
    Lai, Yi-Wei
    Lee, Kan-Rong
    Yang, Seng-Yu
    Tseng, Chung-Jen
    Jang, Shian-Ching
    Tsao, I-You
    Chen, Szu-yuan
    Lee, Sheng-Wei
    CERAMICS INTERNATIONAL, 2019, 45 (17) : 22479 - 22485
  • [24] Potentiality of cobalt-free perovskite Ba0.5Sr0.5Fe0.9Mo0.1O3-δ as a single-phase cathode for intermediate-to-low-temperature solid oxide fuel cells
    Ling, Yihan
    Zhang, Xiaozhen
    Wang, Zhenbin
    Wang, Songlin
    Zhao, Ling
    Liu, Xingqin
    Lin, Bin
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2013, 38 (33) : 14323 - 14328
  • [25] La0.4Bi0.4Sr0.2FeO3-δ as Cobalt-free Cathode for Intermediate-Temperature Solid Oxide Fuel Cell
    Li, Mei
    Ren, Yuyu
    Zhu, Zhesheng
    Zhu, Shiyue
    Chen, Fanglin
    Zhang, Yanxiang
    Xia, Changrong
    ELECTROCHIMICA ACTA, 2016, 191 : 651 - 660
  • [26] Cobalt-free oxide Ba0.5Sr0.5Fe0.8Cu0.2O3-δ for proton-conducting solid oxide fuel cell cathode
    Zhao, Ling
    He, Beibei
    Ling, Yihan
    Xun, Zhiqing
    Peng, Ranran
    Meng, Guangyao
    Liu, Xingqin
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2010, 35 (08) : 3769 - 3774
  • [27] High performance cobalt-free perovskite cathode for intermediate temperature solid oxide fuel cells
    Niu, Yingjie
    Zhou, Wei
    Sunarso, Jaka
    Ge, Lei
    Zhu, Zhonghua
    Shao, Zongping
    JOURNAL OF MATERIALS CHEMISTRY, 2010, 20 (43) : 9619 - 9622
  • [28] A Novel Self-Assembled Cobalt-Free Perovskite Composite Cathode with Triple-Conduction for Intermediate Proton-Conducting Solid Oxide Fuel Cells
    Tong, Hua
    Fu, Min
    Yang, Yang
    Chen, Fanglin
    Tao, Zetian
    ADVANCED FUNCTIONAL MATERIALS, 2022, 32 (48)
  • [29] A cobalt-free SrFe0.9Sb0.1O3-δ cathode material for proton-conducting solid oxide fuel cells with stable BaZr0.1Ce0.7Y0.1Yb0.1O3-δ electrolyte
    Ling, Yihan
    Zhang, Xiaozhen
    Wang, Songlin
    Zhao, Ling
    Lin, Bin
    Liu, Xingqin
    JOURNAL OF POWER SOURCES, 2010, 195 (20) : 7042 - 7045
  • [30] Thermal Decomposition of Cobalt-free SrFe0.9Ti0.1O3-δ Cathode for Intermediate Temperature Solid Oxide Fuel Cell
    Baharuddin, Nurul Akidah
    Muchtar, Andanastuti
    Somalu, Mahendra Rao
    Samat, Abdullah Abdul
    PROCEEDING OF 4TH INTERNATIONAL CONFERENCE ON PROCESS ENGINEERING AND ADVANCED MATERIALS (ICPEAM 2016), 2016, 148 : 72 - 77
12345