Selective oxidation of nitrocompounds by dimethyldioxirane

被引：8
|
作者：
Ballini, R [1 ]
Papa, F [1 ]
Bovicelli, P [1 ]
机构：
[1] UNIV ROMA LA SAPIENZA, DIPARTIMENTO CHIM, CTR STUDIO CHIM SOSTANZE ORGAN NAT, I-00185 ROME, ITALY
来源：
TETRAHEDRON LETTERS | 1996年 / 37卷 / 20期
关键词：
D O I：
10.1016/0040-4039(96)00598-9
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An efficient monooxidation of nitrodiols was performed by dimethyldioxirane, exploiting the inhibiting effect of the nitro group on reaction at adjacent centers. The reaction appears of general value when an alcoholic moiety is in alpha or beta to the nitro group. A double bond was similarly deactivated towards epoxidation, and other functional groups reacted preferentially. Copyright (C) 1996 Published by Elsevier Science Ltd
引用
收藏
页码：3507 / 3510
页数：4
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