Synthesis and Crystal Structure of Coordination Polymer [Sc2(HOCH2CH2OH)4(tFBDC)3] • 2HOCH2CH2OH

被引：5

作者：

Cheplakova, A. M. ^{[1
,2
]}

Samsonenko, D. G. ^{[1
,2
]}

Fedin, V. P. ^{[1
,2
]}

机构：

[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk, Russia

[2] Novosibirsk State Univ, Novosibirsk, Russia

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2019年 / 60卷 / 02期

基金：

俄罗斯基础研究基金会;

关键词：

scandium complexes; metal-organic coordination polymer; tetrafluoroterephthalic acid; crystal structure; FRAMEWORKS;

D O I：

10.1134/S002247661902015X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The heating of a mixture of as-precipitated scandium hydroxide and tetrafluoroterephthalic acid in ethylene glycol leads to the formation of the complex [Sc-2(HOCH2CH2OH)(4)(tFBDC)(3)]2HOCH(2)CH(2)OH (tFBDC(2-) = tetrafluoroterephthalate) (1). According to the X-ray data, compound 1 is a chain coordination polymer. Sc(III) cations and tFBDC(2-) anions form double chains (ribbons). The coordination number of Sc(III) is completed to seven by ethylene glycol molecules acting as chelate ligands. There is a complex system of hydrogen bonding interactions induced by oxygen atoms of carboxylic groups of perfluorinated ligands and coordinated and lattice ethylene glycol.

引用

页码：289 / 293

页数：5

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