Fabrication of Conjugated Polymer Hybrid Thin Films with Radially Oriented Aluminosilicate Nanofibers by Spin-Assembly

被引：13
|
作者：
Jiravanichanun, Nattha [1 ]
Yamamoto, Kazuya [1 ]
Yonemura, Hiroaki [2 ]
Yamada, Sunao [2 ,3 ]
Otsuka, Hideyuki [1 ]
Takahara, Atsushi [1 ]
机构：
[1] Kyushu Univ, Inst Mat Chem & Engn, Nishi Ku, Fukuoka 8190395, Japan
[2] Kyushu Univ, Fac Engn, Dept Appl Chem, Nishi Ku, Fukuoka 8190395, Japan
[3] Kyushu Univ, Ctr Future Creat, Fukuoka 8190395, Japan
来源：
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 2008年 / 81卷 / 12期
关键词：
D O I：
10.1246/bcsj.81.1663
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Multilayer hybrid films of imogolite nanofibers and water-soluble poly(p-phenylene) (WS-PPP) were prepared by two assembly methods. Layer-by-layer (LBL) assembly and spin-assembly were applied to fabricate the hybrid films. The deposited amount of WS-PPP per thickness was not significantly different between the two methods. However, the spin-assembly method gave significant orientation of imogolite nanofibers aligned in the radial direction, while imogolite nanofibers were randomly networked in the LBL film. The results suggested that lyotropic mesophase of imogolite and centrifugal and shear forces influenced a self-assembly of imogolite fibers oriented in a force-inducing direction.
引用
收藏
页码：1663 / 1668
页数：6
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