Reduction of organic azides to amines using reusable Fe3O4 nanoparticles in aqueous medium

被引：42
|
作者：
Pagoti, Sreenivasarao [1 ,2 ]
Surana, Subham [1 ]
Chauhan, Ajay [1 ]
Parasar, Bibudha [1 ]
Dash, Jyotirmayee [1 ,2 ]
机构：
[1] Indian Inst Sci Educ & Res Kolkata, Dept Chem Sci, Mohanpur 741252, W Bengal, India
[2] Indian Assoc Cultivat Sci, Dept Organ Chem, Kolkata 700032, W Bengal, India
来源：
CATALYSIS SCIENCE & TECHNOLOGY | 2013年 / 3卷 / 03期
关键词：
ASYMMETRIC TRANSFER HYDROGENATION; SOLVENT-FREE; SELECTIVE HYDROGENATION; CATALYZED AMINATION; CLICK CHEMISTRY; ARYL HALIDES; IRON; NITROARENES; CONVERSION; HYDRAZINE;
D O I：
10.1039/c2cy20776a
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Aromatic, heteroaromatic and sulfonyl azides were conveniently reduced to the corresponding amines in excellent yields using hydrazine hydrate in the presence of iron oxide nanoparticles. The Fe3O4-MNPs could be easily separated by an external magnet, and recycled ten times without significant loss of the catalytic efficiency.
引用
收藏
页码：584 / 588
页数：5
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