Reduction of organic azides to amines using reusable Fe3O4 nanoparticles in aqueous medium

被引：42

作者：

Pagoti, Sreenivasarao ^{[1
,2
]}

Surana, Subham ^{[1
]}

Chauhan, Ajay ^{[1
]}

Parasar, Bibudha ^{[1
]}

Dash, Jyotirmayee ^{[1
,2
]}

机构：

[1] Indian Inst Sci Educ & Res Kolkata, Dept Chem Sci, Mohanpur 741252, W Bengal, India

[2] Indian Assoc Cultivat Sci, Dept Organ Chem, Kolkata 700032, W Bengal, India

来源：

CATALYSIS SCIENCE & TECHNOLOGY | 2013年 / 3卷 / 03期

关键词：

ASYMMETRIC TRANSFER HYDROGENATION; SOLVENT-FREE; SELECTIVE HYDROGENATION; CATALYZED AMINATION; CLICK CHEMISTRY; ARYL HALIDES; IRON; NITROARENES; CONVERSION; HYDRAZINE;

D O I：

10.1039/c2cy20776a

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Aromatic, heteroaromatic and sulfonyl azides were conveniently reduced to the corresponding amines in excellent yields using hydrazine hydrate in the presence of iron oxide nanoparticles. The Fe3O4-MNPs could be easily separated by an external magnet, and recycled ten times without significant loss of the catalytic efficiency.

引用

页码：584 / 588

页数：5

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