Formation of highly ordered Ca-overlayers on TiO2(110) surfaces studied by scanning tunneling microscopy and atomistic simulation

被引：10
|
作者：
Nörenberg, H
Harding, JH
机构：
[1] Univ Oxford, Dept Mat, Oxford OX1 3PH, England
[2] Univ London Univ Coll, Dept Phys & Astron, London WC1E 6BT, England
来源：
APPLIED SURFACE SCIENCE | 1999年 / 142卷 / 1-4期
基金：
英国工程与自然科学研究理事会;
关键词：
Ca-overlayers; TiO2(110) surfaces; scanning tunneling microscopy; atomistic simulation;
D O I：
10.1016/S0169-4332(98)00670-9
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
An ordered surface layer of Ca on TiO2(110) has been prepared and studied after annealing of a TiO2-rutile crystal, During the annealing process Ca impurities from the bulk segregate to the surface. A well ordered p(3 x 1) reconstruction has been observed by scanning tunneling microscopy (STM). Calculations have shown that the p(3 x 1) reconstruction has the lowest energy. Every third Ca ion in the [001] direction is elevated by around 1 Angstrom. Therefore, the STM contrast is mainly due to calcium and caused by geometry rather than electronic effects. (C) 1999 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：174 / 176
页数：3
相关论文
共 50 条
  • [21] Local electronic states of TiO2(110) surface investigated by scanning tunneling microscopy and scanning tunneling spectroscopy
    Minato, T
    Sainoo, Y
    Kim, Y
    Susaki, T
    Shiraki, S
    Kato, HS
    Kawai, M
    Aika, KI
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2004, 227 : U847 - U847
  • [22] In situ scanning tunneling microscopy study of Ca-modified rutile TiO2(110) in bulk water
    Serrano, Giulia
    Bonanni, Beatrice
    Kosmala, Tomasz
    Di Giovannantonio, Marco
    Diebold, Ulrike
    Wandelt, Klaus
    Goletti, Claudio
    BEILSTEIN JOURNAL OF NANOTECHNOLOGY, 2015, 6 : 438 - 443
  • [23] FORMATION OF METAL GAAS(110) INTERFACES STUDIED BY SCANNING TUNNELING MICROSCOPY
    FEENSTRA, RM
    APPLIED SURFACE SCIENCE, 1992, 56-8 : 104 - 116
  • [24] Oxide formation on Si(100)-2×1 surfaces studied by scanning tunneling microscopy/scanning tunneling spectroscopy
    Ikegami, Hiroshi
    Ohmori, Kenji
    Ikeda, Hiroya
    Iwano, Hirotaka
    Zaima, Shigeaki
    Yasuda, Yukio
    Japanese Journal of Applied Physics, Part 1: Regular Papers & Short Notes & Review Papers, 1996, 35 (2 B): : 1593 - 1597
  • [25] PHOSPHORUS VACANCIES AND ADATOMS ON GAP(110) SURFACES STUDIED BY SCANNING TUNNELING MICROSCOPY
    EBERT, P
    URBAN, K
    ULTRAMICROSCOPY, 1993, 49 (1-4) : 344 - 353
  • [26] ADSORPTION OF BISMUTH ON SI(110) SURFACES STUDIED BY SCANNING-TUNNELING-MICROSCOPY
    SAKAMA, H
    KAWAZU, A
    SUEYOSHI, T
    SATO, T
    IWATSUKI, M
    JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 1993, 32 (6B): : 2929 - 2933
  • [27] Scanning tunneling microscopy of porphyrin-based molecules on TiO2 surfaces
    Inada, M
    Scifo, L
    Tanaka, S
    Grevin, B
    Suzuki, H
    Mashiko, S
    JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS BRIEF COMMUNICATIONS & REVIEW PAPERS, 2006, 45 (3B): : 2103 - 2105
  • [28] Noncontact scanning nonlinear dielectric microscopy imaging of TiO2(110) surfaces
    Kin, Nobuhiro
    Cho, Yasuo
    JOURNAL OF VACUUM SCIENCE & TECHNOLOGY B, 2010, 28 (03):
  • [29] Scanning Tunneling Microscopy Visualization of Polaron Charge Trapping by Hydroxyls on TiO2(110)
    Yim, Chi-Ming
    Allan, Michael
    Pang, Chi Lun
    Thornton, Geoff
    JOURNAL OF PHYSICAL CHEMISTRY C, 2024, 128 (33): : 14100 - 14106
  • [30] Structure of epitaxial thin TiO2 films on W(110) as studied by low energy electron diffraction and scanning tunneling microscopy
    Herman, GS
    Gallagher, MC
    Joyce, SA
    Peden, CHF
    JOURNAL OF VACUUM SCIENCE & TECHNOLOGY B, 1996, 14 (02): : 1126 - 1130
12345